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Polymer questions No Brin is Too Smallreally聚合物的问题不太smallreally脑.docx

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Polymer questions No Brin is Too Smallreally聚合物的问题不太smallreally脑

? No Brain Too Small ? CHEMISTRY ? AS 90698 Describe aspects of organic chemistry COLLATED POLYMER QUESTIONS - polyesters, polyamides and peptides (2011:2) Nylon 6,6 is a polymer with the following structure: (a) Circle an amide linkage in the structure above. (b) Draw TWO monomers that could have formed this polymer. (c) Nylon 6 is formed from the monomer H2N – (CH2)5 – CO2H. (i) Name this monomer. (ii) Draw THREE repeating units of the Nylon 6 polymer chain. (d) Nylon is used for making ropes for climbing and abseiling. The ropes come with a warning label attached, such as that shown below. WARNING!!! Nylon Rope: Do not allow to come in contact with acids or their vapours Discuss why this warning label is attached to nylon rope when purchased. Include in your answer: ? the type of reaction that would occur ? relevant organic structural formulae ? any changes to the properties of the nylon rope 2010 (3) The polymer commonly known as Kevlar is used to make bullet-proof vests and bicycle tyres. It can be made in a condensation reaction from either of the following pairs of monomers: However, the second pair of monomers needs to be heated for the polymerisation reaction to take place. Note: is a benzene ring and should be treated as a hydrocarbon chain. It is not a functional group and does not change during the reaction. Discuss these polymerisation reactions. Your answer should include: a repeating unit of the polymer chain reasons for the choice of monomers identification of the functional group in the polymer a reason why this is classified as a condensation reaction a comparison of the two pairs of monomers, including the reason that the second reaction will not take place without heating. 2009 (3) Kodel is a polymer with the following structure: Identify TWO monomers for this structure. Explain why this type of polymer is known as a condensation polymer. Compound X is a polymer which can be hydrolysed to give a single monomer, Compound Y