有机化学2014有机绪论.pptVIP

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * 化合物的1H NMR谱图(500MHz) ? 化合物的13C NMR谱图 1,1,2-三溴乙烷 CH3CH2CH2NO2的NMR谱 通常，只有相邻碳上1H才相互偶合。 CH3CH2OH的NMR谱 C3H7Cl的NMR 2H 2H 3H 芳香酮C8H7ClO的NMR谱 (连在羰基上) 核磁共振的应用 1、有机物、未知物结构测定 2、定性分析、定量分析（含药物分析） 3、在医学上的应用 化合物 的MS谱图 七 确定有机化合物结构的方法及步骤 结构的确定（波谱分析-四谱分析-17章） 质谱：MS(mass spectra) 优点：凭借极少量样品10-9g即能获得有关相对分子质量、分子结构的大量信息。尤其是近年将气相色谱(gas chromatography，GC)、高效液相色谱(high performance liquid chromatgraphy, HPLC)等分别与MS连用，使得气-质连用仪（GC-MS）和液-质连用仪（LC-MS）成为分析、鉴定微量天然化合物、生物活性物质最为有效的工具。 SUMMARY An organic compound is a chemical compound of carbon, which is called as hydrocarbon or its derivative too. Organic chemistry was the chemistry which studies compounds of carbon. Nowadays, Organic chemistry is the science which studies the source, preparation, structure, performance, usage, function and relevant theories as well as disciplines of the methods of organic compounds. SUMMARY Organic compounds are of covalent bond there are two kinds of covalent bonds--σ bond and πbond in the organic compounds. The structure of a comprises construction, configuration and conformation of the molecule, which are the prerequisite knowledge that is used to study the chemical behaviors of the molecule, activity functions and reaction laws among the molecules. SUMMARY Isomerism of organic compounds means that the compounds are of the same molecular formula, but their molecular structures are different from each other. Isomerism of organic compound comprises construction isomerism and stereo isomerism of the molecule. And stereo isomerism of the organic molecule is divided into configuration isomerism and conformation isomerism of the molecule. SUMMARY And stereo isomerism of the organic molecule is divided into configuration isomerism and conformation isomerism of the molecule. Isomerism is essential for chemistry and biology to express the material characteristics of changing and sele