沸石在水处理中的应用究毕业论文.docx

摘要氨氮是引起水体富营养化和环境污染的重要物质，采用沸石去除水中氨氮是水污染控制领域的研究热点之一。沸石是一种廉价的非金属矿物，具有独特的吸附和离子交换性能。天然沸石在改性过程中, 硅的质量分数显著减少，而钠的质量分数增多. 这样有利于NH4+-N的交换反应，因此改性沸石对氨氮的吸附NH4+-N的性能加强。本研究首先对天然沸石进行了改性，确定了最佳的改性条件，并通过采用动态法研究改性沸石吸附柱去除微污染水源中氨氮的规律，包括改性沸石的粒径大小、入水流速、初始氨浓度等参数的影响，绘制穿透曲线。通过研究，本文得出了以下结论：①沸石改性的最佳条件为：NaCl溶液浓度3mol/L，水浴温度70～75℃，时间3h；②NaCl改性沸石的去除率明显高于未改性的。相比之下对氨氮的去除率增加了8%；③沸石粒径越小，去除率越高，改性效果越好。沸石粒径在0.5-1mm是对氨氮的去除率最高；④入水流速越小，改性沸石对氨氮的去除率越高；⑤废水的初始浓度越低，改性沸石对氨氮的去除率越高。最高可到达74%.关键词：改性沸石氯化钠氨氮吸附AbstractAmmonia-nitrogen(NH4+)is an important contaminant foreutrophication of water bodies and environmental pollution.Zeolite is a cheap non-metallic minerals,with unique adsorption and ion -exchange performance。After natural zeolite is modified quality score of silicon significantly reduces，Andquality score of Sodiumincreases。It helps in ammonium-ion exchange，so dsorption performance of modified zeolite strengthens。Atfirst the natural zeolite was modified by chemical approaches in the research,and choose thebest modifyingcondition of zeolite.Then study its treatment effect of low concentration NH4+in columnreactor and draw breakthrough curve, investigating such factors as pellet size, velocityof flow and nitial ammonia concentration etc. The main results of this research were as follows:ⅠUnder these circumstances:,c=3mol/l,T=70～75℃,the modification time3hours，we can get the the right modified zeolite; Ⅱ removal efficiency of zeolite modified withfor ammonia nitrogen is significantly higher than unmodified 。In contrast to ，removal rate of ammonia nitrogenincreasesby 8%;ⅢThe smaller the modified zeolite particle size, the higher the modification ；Ⅴthe water velocity is smaller, removal of ammonia nitrogen is higher;Ⅳwastewater concentration is lower, the modified zeolite of removal rate of ammonia nitrogenis higher . The highest removal rate can reach 74 percent .Key words：modified zeolite NaCl ammonia nitroge wastewater adsorption目 录1 绪论11.1 水体中氨氮污染现状概况11.1.1 水体中氨氮污染的现状11.1.2各国水质中氨氮的标准11.1.3氨氮的来源11.1.4 氨氮的