高比能量锂硫原电池的研制并分析.pdfVIP

高比能量锂／硫原电池的研制 热处理制得的碳硫复合物正极材料制作的薄层正极，具有最佳的放电性能。 利用热处理法制备单质硫一碳纳米管复合材料，采用双层涂覆的方法制作薄层正 极，组装锂／硫实体原电池。实验结果表明，约80％单质硫嵌入碳材料的孔隙中， 常温下放电，放电比比容量为627 mAh·g-1，比能量为1439Wh·埏～。60℃恒流 放电，放电比容量为730 mAh·g-1，比能量为1643Wh·kg-1。 关键词：N／硫电池；正极；复合材料；放电性能 lI 高比能量锂，硫原电池的研制 STUDYOFkI THI BATTERI ESWI THHl GHENERGY UM／SULFUR Name：ZhuoHua-lan Major：PhysicalC枷stry Supervisor：Pro￡YuanZhong-zhi ABSTRACT Lithium／Sulfurbatterieshavereceivedextensiveattentionbecauseofits high hasthe oflithiumbatteriesincurrent． specificcapacity．Ithighestspecificcapacity exhibitslow and cathodewhichcontains However,sulfur utilization，the conductivity 100％sulfurhas electrical iscriticalto the poor properties．Therefore，itmodify cathodematerial．This different paperpreparedcompositesby method，prepared differentcathodewimdifferentthicknessesandselectedthebest and composite methodto Li／S werecharacterizedXRD、TG、 preparebattery．Thecomposites by SEM、TEMandBET．The was withthebatteriesin dischargeexperimentperformed different temperature． Asulfur-activatedcarbon was sulfurand compositesynthesizedbybailing activatedcarbon．Cathodeswere bysulfurandsulfur-activatedcarbon prepared resultsof showedthatsulfurhadembedded compos