激光熔注单晶颗粒增强wcpti-6al-4v梯度复合材料层的界面反应机理-interfacial reaction mechanism of single crystal particles reinforced wcp ti - 6al - 4v gradient composite layer by laser fusion.docx

哈尔滨工业大学工学博士学位论文哈尔滨工业大学工学博士学位论文AbAbstract-- PAGE VIII III -在热力学分析的基础上，借助热模拟试验，研究了WCp/Ti界面反应机理， 并根据W2C层发生的孪生变形现象，合理解释了固态相变条件下W2C与母相WC 不形成共格界面的原因，澄清了WCp/Ti界面反应存在的争议问题。通过快速、 缓慢凝固条件下WCp/Ti界面反应行为的对比研究，证实了快速凝固条件下形成 的反应层结构具有抑制界面反应的作用。结果表明，W2C层是固相WC与液态Ti 反应生成的， W2C 内部发生的孪生变形，破坏了 WC/W2C 共格界面，在单晶 W2C层形成了W2C孪晶。在界面反应过程中形成的致密TiC层能够能够将WC颗 粒和与熔池隔离，控制WC颗粒分解，可以抑制界面反应的进行。关键词：激光熔注；梯度复合材料层；单晶增强相；界面反应；断裂行为AbstractProtecting titanium alloys with a particulate reinforced metal matrix composites (MMCs) coating is a promising solution to improve their surface properties while keeping the advantageous bulk properties unaffected, which exhibits great advantage in academic study and practical application. However, there are two main problems to be resolved in the preparation of MMCs coating, namely excessive melting of the reinforced particle and the high crack tendency of the MMCs coating. Graded transition in composition between the MMCs coating and the substrate has been proved to be one of the most effective ways to restrain the crack of the coating. A graded MMCs coating can be produced by introducing an interlayer, which can decrease the crack tendency of the MMCs coating to some degree. Nevertheless, this solution can not resolve the excessive melting of reinforced particle. Moreover, introducing an interlayer clearly increases the difficulity of the production process.To solve above problems, laser melt injection (LMI) was introduced, by injecting the single crystal WC particles (WCp) directly into a laser melt pool, the LMI process successfully realized the fabrication of the graded WCp/Ti-6Al-4V MMCs coating without the introduction of the interlayer. Based on the study of the LMI process, the formation mechanism of the graded MMCs coating was investigated by means of numerical simulation of the flow and temperature field of the melt. In addition, the solidification process of the laser melt pool, the fracture behaviour of the MMCs coating and the WCp/Ti interfacial reaction were