不同活化方法对开心果壳活性炭的孔结构影响4.docVIP

不同活化方法对开心果壳活性炭的孔结构影响陈虹霖1，宋 磊2收稿日期：收稿日期： 年 月 日通信作者：宋磊，硕士生导师，主要从事环境材料研究。E-mail： HYPERLINK mailto:songlei@ songlei@、联系电话基金项目：华侨大学基本科研业务费专项基金资助（JB-ZR1150）；华侨大学高层次人才科研启动基金（NO.11BS215）（1，2华侨大学化工学院，福建 厦门 361021）摘 要：本文以开心果壳为原料制备活性炭，通过在－196℃下测定活性炭的氮气吸脱附等温线，探讨ZnCl2法、KCl法以及ZnCl2-KCl-H2O联合活化法对活性炭孔结构的影响。研究表明，ZnCl2法制备的开心果果壳活性炭以微孔为主，采用40 %ZnCl2溶液浸渍、在500 ℃下活化1.5 h后得到的活性炭的比表面积为630 m2/g；单独KCl活化法不能起到较好的活化效果；对于ZnCl2活化法和KCl活化法，增加水蒸气活化都能增强活化效果，尤其对KCl活化的增强效果最为明显，使其比表面积增大了近9倍，但其孔结构仍是微孔为主；ZnCl2-KCl-H2O联合活化法能有效增加活性炭的中孔，采用40 %ZnCl2和6 %KCl溶液浸渍，在900 ℃下活化1.5 h后得到的活性炭的中孔添加量为关键词：开心果壳；活性炭；孔结构; 中孔添加中图分类号：X705 文献标识码：A 文章编码：The Effect of Different Activation Methods on The Pore Structure of Activated Carbons Prepared from Pistachio ShellsCHEN Hong-lin1, SONG Lei2(1,2School of Chemical Engineering, Huaqiao University, Xiamen 361021, China)Abstract: Activated carbons was prepared from Pistachio nut shells by using ZnCl2, KCl and ZnCl2-KCl-H2O as activated agents， and were tested at －196 ℃ to obtain the N2 adsorption isotherms to get the pore and surface properties. It showed that the pore structure of ZnCl2-activated carbons was main micropore, and the max BET area of the activated carbons was 630 m2/g. Using KCl as activeated agent, the BET area was only 70 m2/g. The activation effect was improved by introducing vapor as the activation gas by using ZnCl2 and KCl as activated agent. Addition H2O as the activation gas played a much more important role on addition new pore, especially for the method of KCl, and it’s BET area increased by about 9 times, and the pore structure was main micropore. Mesopore was effectivlely donated by using ZnCl2-KCl-H2O as mixed activated agents. Under the condition of impregnating with 40 %ZnCl2 and 6 %KCl, the BET area of the activated carbons was 740 m2/g for 1.5 hours activated time on 900 ℃, and the mesoporous volume was 0.10 cm3/g, Key words: pistachio nut shell; activated carbon; pore structure；mesopore addition活性炭( activated carbon，简称 AC) 是