耐酸微生物在难降解有机污染废水中的应用探索摘要工业废水难.DOC

J. Serv. Sci. Management, 2009, 2: ** Published Online****** 2009 in SciRes ( HYPERLINK http://www.SciRP.org/journal/jssm www.SciRP.org/journal/jssm) Copyright ? 2009 SciRes JSSM 耐酸微生物在难降解有机污染废水中的应用探索 摘 要：工业废水难降解有机污染物处理是当前水环境修复面临的重大问题。Fenton氧化在难生物降解有机物去除方面具有独特优势，但在实际应用中面临诸如酸碱消耗多、H2O2投加量大的技术障碍。本论文基于中性pH条件Fenton氧化与耐酸菌降解组合新工艺，针对Fenton单元的酸性出水，主要含有一些简单有机酸，采用耐酸菌群进行后续处理，实现COD去除和pH提升。首先，分析了耐酸菌群的组成，考察了pH值、H2O2浓度、碳源种类、温度的影响；其次，启动运行负载耐酸菌群的生物活性炭反应器（BAC），对有机酸模拟配水以及Fenton酸性出水进行处理，获取一些工艺操作参数，为新工艺的应用提供理论依据。 关键词：难降解有机污染物；芬顿氧化；耐酸菌；生物活性炭工艺 Abstract: Removal of refractory organic pollutants in industrial wastewaters is a significant problem nowadays in remediation of aquatic environment. Fenton technique poses specific advantages in the destruction of hardly biodegradable organics, however, it is confronted with serious drawbacks in practical application involving great consumption of acid and base, and high H2O2 dosage. Based on a new coupled process of Fenton oxidation under neutral pH and post-treatment by acid-tolerant microbes, this paper used special acid-tolerant microbes to dispose of acidic effluent from Fenton which consists of some simple organic acids, aimig at COD removal and pH increase. Firstly, the composition of acid-tolerant microbes was explored and effects of pH, H2O2, carbon source and temperature were investigated. Secondly, a biological activated carbon (BAC) reactor innoculated with acid-tolerant microbes was started up and then run for a long time. Some operation parameters for BAC running were obtained in the treatment of artificial wastewater including acetic acid and Fenton effluent. This study will provide a solid basis for the future application of the new coupled Fenton and biological processes. Keywords: Refractory organic pollutants; Fenton oxidation; Acid-tolerant bacteria; Biological activated carbon (BAC). 1 前言 随着我国工业的迅猛发展，工业废水污染问题愈加受到重视，多年来工业废水排放量一直占我国废水总排放量的40%以上[1