双键离子液体接枝固载PDVB的特性和其催化油酸甲酯化反应.docVIP

双键离子液体接枝固载PDVB的特性及其催化油酸甲酯化反应的研究 蔡绍雄 张慧 孟松涛 郑德勇* 卢泽湘 廖益强 基金项目：国家自然科学基金 基金项目：国家自然科学基金 收稿日期：2016-12-28 作者简介：蔡绍雄，男，1991年出生，硕士，生物质能源研究 通讯作者：郑德勇，男，1966年出生，副教授，林产化工和生物质能源研究 （福建农林大学 材料工程学院，福州 350000） 摘 要：以二乙烯基苯（DVB）为单体，采用沉淀聚合法来合成单分散多孔聚二乙烯基苯微球（PDVB），利用PDVB微球上悬挂双键与带双键的离子液体单体进行接枝共聚反应，制备了PDVB-IL固体酸，用SEM、BET、FT-IR和TG进行表征，并将其用于催化油酸与甲醇进行酯化反应制备油酸甲酯。结果表明：PDVB-IL固体酸的微粒为球形规整，颗粒均匀，比表面积为451.12 m2/g，耐热性能优异，热分解温度达350 ℃；将催化剂应用于酯化反应，在反应温度为90 ℃ 关键词：聚二乙烯基苯离子液体 PDVB-IL固体酸 酯化反应 油酸甲酯 中图分类号：TQ646 文献标识码：A 文章编号：（ ）The?characteristics?of?double bond ionic liquids?copolymerizate on PDVB HYPERLINK javascript:void(0); and?synthesis of methyl oleate catalyzed CAI Shao-xiong ZHANG Hui MENG Song-tao ZHENG De-yong* LU Ze-xiang LIAO Yi-qaing （College of Material Engineering, Fujian Agriculture And Forestry University, Fuzhou 350000, China） Abstract: Taking divinylbenzene (DVB) as the monomer, porous monodisperse PDVB microspheres was synthesized by precipitation polymerization (PDVB). The residual double bond on PDVB microsphere surface and the double bond of the ionic liquid were used for copolymerization reaction, and the PDVB-IL solid acid was prepared. The obtained PDVB-IL solid acid was characterized by SEM, BET, FT-IR and TG, and then applied for the preparation of methyl oleate by oleic acid and methanol. The results showed that the PDVB-IL had good spherical morphology, uniform particle size, specific surface area was 451.12 m2/g, and the PDVB-IL had good thermal stability, which its decomposition temperature was up to 350 ℃. The effects of the oleic acid conversion rate has been investigated, Under this condition of that, the reaction temperature 90 ℃, molar ratio of methanol to oil 20:1(n : n), catalyst dosage 4% (based on the mass of oleic acid) and reaction time 5 h, the yield of methyl oleate was 93.02%. Solid acid of PDVB-IL could be used for 5 times with high catalytic activity. Key words: HYPERLINK javascript:void(0); Poly? HYPERLINK javascript:void(0); divinyl? HY