StudyonSurfaceModificationofTitaniumDioxide二氧化钛的表面改性.PDFVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2018, 8(3), 191-198 Published Online May 2018 in Hans. /journal/hjcet /10.12677/hjcet.2018.83024 Study on Surface Modification of Titanium Dioxide Chenglong Duan1,2, Zhenbin Chen1,2*, Xiaojiao Liu1,2, Xudong Wang1,2, Xueyan Du1,2 1 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou Gansu 2 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou Gansu th th th Received: May 9 , 2018; accepted: May 17 , 2018; published: May 24 , 2018 Abstract Surface of titanium dioxide (TiO ) was modified with silane coupling agent γ-(Methacryloxypropyl) 2 trimethoxy Silane (KH570). The graft ratio (Gr) of TiO2 was characterized by the silicon molybde- num blue method. Taking the graft ratio of KH570 as an index, effects of pH, the mass ratio of KH570 to TiO2, reaction time, reaction temperature and the mush number of TiO2 on the graft ra- tio were researched through single-factor experiment. The optimum process conditions of surface modification of TiO2 were as follows: the modification pH was 7.0; the mass ratio of KH570 to TiO2 was 0.30; the modification time was 24 h; the modification temperature was 45˚C and the mush number of TiO2 was 150. The result of Fourier transform infrared (FTIR) showed that there ex- isted bonding interaction between KH570 and the surface of TiO2. Keywords Titanium Dioxide, Surface Modification, Optimum Process Condition 二氧化钛的表面改性研究 1,2 1,2* 1,2 1,2 1,2 段成龙 ，陈振斌 ，刘晓