东华大学物理化学考研-9复习题部分答案.pptVIP

(1) ΔU = Δ H = 0 1. ΔG = nRT ln ( p2 / p1 ) = 1×8.314×298.2× ln 6 = 4442.2 J W = - nRT ln ( p1 / p2 ) = - 1×8.314×298.2× ln(1/ 6) = 4442.2 J Q = - W = - 4442.2 J ΔS = nR ln ( p1 / p2 ) = 1×8.314× ln(1/ 6) = -14.9 J·K-1 (2) ΔU = Δ H = 0 ΔS = -14.9 J·K-1 ΔG = 4442.2 J W = -p( V2 – V1 ) = -p2( nRT2 /p2 – nRT1 /p1 )= -nRT(1- p2 /p1) = -1×8.314×298.2× (1- 6) = 12.4 kJ 2. ?G1?0 ?G2=0 ?G4=0 ?G5?0 3. Kθ = Kc(RT / pθ)?n Kc= 1.34×10-3 mol·dm-3 a 140.32×10-4 4. 解:(a) Pt│H2(g)│H+(aq)│O2(g)│Pt (-)