梳状聚合物分散剂 稳定剂Agrilan 755 China April, 2012 CN.pptVIP

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梳状聚合物分散剂 稳定剂Agrilan 755 China April, 2012 CN.ppt

Akzo Nobel Surfactants - Agro Seminar - Suspension Concentrate Surface Chemistry - AGRO Applications Surface Chemistry Surface Chemistry - AGRO Applications Agrilan 755 – Stabilizer Our new comb-polymeric dispersant 梳状聚合物 稳定剂 / 分散剂 Surface Chemistry Agrilan 755 - Comb polymers Hydrophobic back bone (憎水主链) Hydrophilic chains (亲水) Excellent stabilizers for SC and SE (优异的对SC和SE的稳定性) Excellent dispersants for SC and SE – steric stabilization (优异的对SC和SE的分散性能 – 空间立体稳定性) High molecular weight (高分子量) Surface Chemistry Surface Chemistry * Agrilan 755 Over the past few years pesticide formulations have become more complex – 在过去的若干年里,农药的成分越来越复杂 Multiple actives in SC悬浮剂中更多的原药成分 Suspoemulsions (SE 悬乳剂 ) – dispersed and emulsified phases 悬乳剂中同时含有分散相和乳化相 As 分散剂 stabilizers 稳定剂 with multiple actives or when an oil phase is included 在多种原药或者有油相存在的系统中,作为分散剂和稳定剂。 Surface Chemistry Agrilan 755 Stabilizer (Agrilan 755 稳定剂) How it works (工作原理) Many anchoring group per molecule of the hydrophobic backbone adsorbs onto the surface of a particle 憎水主链上的大量特殊基团吸附于原药表面 Hydrophilic PEG chains extend into the aqueous phase providing steric stabilization (亲水PEG链伸展入,提供了很好的空间稳定性) (-) (-) (-) (-) (-) Weak anionic groups provide electrostatic repulsion 弱阴离子基团提供电荷排斥 Convention dispersant/Emulsifier 传统的分散/乳化剂 Polymeric dispersant/Emusifier 聚合分散/稳定剂 Active Active Surface Chemistry Hydrophilic PEG chains extend into the aqueous phase providing steric stabilization (亲水PEG链在伸展入均相介质,提供了很好的空间稳定性) (-) (-) (-) (-) (-) Weak anionic groups provide electrostatic repulsion 弱阴离子基团提供静电排斥 Attraction 吸引力 Repulsion排斥力 Distance curve between 2 particles (两微粒间距曲线) 空间稳定性 静电稳定性 静电+空间稳定性 (-) (-) Agrilan 755 Stabilizer (Agrilan 755 稳定剂) How it works (工作原理) Active (-) (-) (-) (-) (-) (-) Active (-) Surface Chemistry Surface Chemistry * Why Agrilan 755 plus another dispersant (Morwet D 425)? 为什么Agrilan 755其他分散剂(Morwet D425)配合使用效果更好? Morwet dispersants are more anionic (polar) than Agrilan 755 – the c

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