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View Article Online / Journal Homepage / Table of Contents for this issue
EQUILIBRIUM BETWEEN MICELLES AND SIMPLE
. IONS, WITH PARTICULAR REFERENCE TO
6
3
: THE SOLUBILITY OF LONG-CHAIN SALTS.
3
2
:
5
1 BY R. C. MURRAYAND G. S.HARTLEY(London).
5
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0
2
/ Received 3rd August, 1934.
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/
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n In 1927,Jones and Bury,l in discussing their freezing-point data
o
l for aqueous solutions of butyric acid, pointed out that these showed
l
u a sudden departure from the normal within a small range of concentra-
H
f tion, and that this was a natural consequence of the law of mass action
o
y where micelles containing a considerable number of simple molecules
t
i
s
r were formed. Later, Grindley and BuryY2 and Davies and BuryYa
e
v
i extended this principle to a study of the partial specific volumes of butyric
n
U acid and potassium octoate in aqueous solution and found that these
y
b properties also showed fairly abrupt changes in the neighbourhood of
d
e
d
a
o
l
n
w
o
D
.
5
3
9
1
y
r
a
u
n
a
J
1
0
n
o
d
e
h
s
i
l
b
u
P
FIG.I.
what they called the “ critical concentration for micelles.” This con-
centration for potassium octoate was in agreement with the evidence
from the freezing-point data of McBain, Laing and title^.^
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