溶剂化电子引发丙烯酸聚合的研究.doc

浦江学院 2017届毕业设计（论文） 题 目：溶剂化电子引发丙烯酸聚合的研究 专 业：高分子材料与工程 班 级： 高材1304 姓 名： 指导老师： 起讫日期：2015.11-2016.06 2016年06 PAGE \* MERGEFORMAT20 PAGE \* MERGEFORMATIII 溶剂化电子引发丙烯酸聚合的研究 摘 要 溶剂化电子是最近20年新拓展的研究方向，对于溶剂化电子的生成方法、结构特征、反应性质以及应用，国内有不少文章中都有叙述，然而对于溶剂化电子在聚合方面的研究却是甚少。 本论文正是从溶剂化电子聚合的方面研究其聚合丙烯酸时的特征。实验反应装置自行搭建，首先，通过金属钠与六甲基磷酰三胺作用，产生溶剂化电子，然后引发丙烯酸的聚合。通过对实验数据的整理和分析，我们对产物的质量、分子量、转化率等方面进行了研究，结果可以看出 ln [M]0/[M] 和t在其反应动力学中是呈现出线性关系的，分子量和转化率呈线性关系，这就表明了在反应过程中活性种是长寿命的。 产物的红外谱图显示，体系是从C=C处进行聚合的。这些说明了该体系具有阴离子聚合以及自由基聚合的性质，但不能说是阴离子聚合，更不能说是自由基聚合。 关键词： 溶剂化电子引发聚合 丙烯酸 反应动力学 红外光谱 核磁氢谱  Polymerization of acrylic acid initiated by the solvated electron Abstract Solvated electrons are the research direction of the new development in the last 20 years. There are many articles in the domestic literature on the formation method, structural characteristics, reaction properties and application of solvated electrons. However, for solvated electrons, is very little. In this paper, the characteristics of acrylic acid polymerization are studied from the aspects of solvent electron polymerization. The experimental reaction device is constructed by itself, firstly, the solvent electron is produced by the effect of sodium metal and six-methyl-P-amide, and then the polymerization of acrylic acid is initiated. Through the sorting and analysis of the experimental data, we study the quality, molecular weight and conversion rate of the product, and the results show that LN [M 1] and T are present in the reaction kinetics; it shows that there is no change in the concentration of active factors in the reaction process. The infrared spectrum of the product shows that the system is aggregated from the C. In addition in the polymerization body. The additi shows that the system has a anion polymerization. And the properties of radical polymerization, but it cant be said to be anionic polymerization. Key Words: Polymerization of the solvent electrons; Acrylic; Reaction Kinetics;