低温高效低泡水基冷轧铝板清洗剂的研究与开发-表面技术
表面技术 第46 卷 第 12 期
·290 · SURFACE TECHNOLOGY 2017 年12 月
低温高效低泡水基冷轧铝板清洗剂的研究与开发
李高峰
(诸暨康星化工科技股份有限公司,浙江 诸暨 311800)
摘 要: 目的 解决冷轧铝板在冬季常温清洗中,由于水温低造成水基清洗剂洗净率低、易发泡等问题。
方法 在3 ℃下研究了两种嵌段醇醚非离子表面活性剂的复配体系的去污性能及其清洗液的泡沫行为,以及
羧酸胺缓蚀剂、烷基磷酸酯OPS75E 的复配体系对钢材、铝材的缓蚀作用。结果 开发了一种在低温下低泡、
高效的水基铝板带清洗剂,最佳配方(以质量分数计):无水偏硅酸钠0.8%~2% ,葡萄糖酸钠5%~8%,羧
酸胺缓蚀剂2%~4% ,OPS75E 1%~3% ,PAA 1%~3% ,有机胺酯TPP 3%~5% ,NF7305 5%~8% ,RPE3110
2%~4% ,水63%~80.2%。在3 ℃及以上温度下,该清洗剂无泡,且能有效抑制清洗中由于油污皂化引起的
泡沫,使用浓度3%、清洗时间2 min 时,对冷轧铝带洗净率可达99%以上。结论 该清洗剂清洗效果较好,
对碳钢、铝材有很好的缓蚀性能,各项性能符合JB/T 4323.1—1999 标准。
关键词:低温;低泡;缓蚀;水基清洗剂;冷轧铝板
中图分类号:TG174.4 文献标识码:A 文章编号:1001-3660(2017)12-0290-05
DOI :10.16490/j.cnki.issn.1001-3660.2017.12.045
Research and Development of High Efficiency Low Foam Water-based
Cleaning Agent at Low Temperature for Cold-rolled Aluminum Sheet
LI Gao-feng
(Zhuji Chem Clean Co. Ltd, Zhuji 311800, China)
ABSTRACT: The work aims to improve cleaning rate under low temperature and reduce foaming of water-based cleaning agent
for cold-rolled aluminum sheet in winter. The cleaning rate and foam behavior of the system mixed with two kinds of block eth-
er nonionic surfactant were studied at 3 ℃ . In addition, the effects of compound system mixed with carboxylic acid amine cor-
rosion inhibitor and alkyl phosphate OPS75E on steel and aluminium products were investigated as well. A water-based cleaning
agent featuring in low foam at low temperature and high efficiency was developed, the optimum formula (on the basis of mass
fraction) was: anhydrous sodium metasilicate 0.8%~2%, sodium g
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