形态可重塑的低温蓄冷相变胶囊.PDF

形态可重塑的低温蓄冷相变胶囊 于得海1，董昊轩2 ，何志祝3 （中国农业大学工学院车辆与工程系，北京 100083） (Tel:010 Email: zzhe@cau.edu.cn) 摘 要：本文提出一种新型低温蓄冷相变胶囊技术，可实现相变胶囊结构形态大尺度重塑，并解决了传统相变胶囊因热胀 冷缩导致封装材料的破裂难题。通过以石蜡球为模板制备了含镓铟液态金属液滴的硅橡胶复合弹性球膜，并灌注乙二醇水溶 o 液作为相变蓄冷材料。实验研究表明，填充在硅橡胶中室温液态金属微纳液滴具有较大过冷度，其冻结行为可发生在-73 C ， 增强了硅橡胶耐低温性能；同时液态金属添加显著提升了硅橡胶热导率（提升幅度可达 6 倍）和可拉伸性能（拉伸率高达 550% ）。胶囊相变传热及形态重塑实验研究表明，相变胶囊在多种形态之间可重复转换并具有优异的蓄冷性能。本文报道 的形态可重塑低温相变胶囊有望在食品冷藏、药品运输及低温蓄冷等应用领域具有潜在的应用价值。 关键词：相变胶囊、液态金属、低温蓄冷、弹性材料 Shape Remodeled PCM Capsule for Cold Storage De-Hai Yu, Hao-Xuan Dong, Zhi-Zhu He (Department of Vehicle Engineering, College of Engineering, China Agricultural University, Beijing 100083) Abstract This paper proposed a novel PCM (phase change material) capsule for cold storage, which could be remodeled for complex shape design and used to eliminate thermal stress induced by the solid-liquid phase transition. Ethylene glycol water solution is considered as PCM and encapsulated with liquid metal (LM) based silicon rubber through shell mold casting with intermediate medium of paraffin wax. The solidification of o LM-silicon has large degree of super-cooling and happens at -73 C. Liquid metal has important impact on the thermal conductivity of rubber (increasing with 6 times higher) and elastic property (stretch rate about 550%).The heat transfer and shape remodeling are both investigated and demonstrated. Shape remodeled PCM capsule reported here may be very useful for food and drug cold chain, and cold storage. Keywords PCM capsule, Liquid metal, Cold storage, Elastic material 0 前言 基于物质的固