《苄叉氰乙酸酯的环氧化反应方法研究》-毕业论文.doc

摘要 环氧化合物是一类用途极广的有机合成中间体。 形成环氧化物的最重要的途径就是烯烃的环氧化反应。环氧化反应无论是在有机合成中还是在化学工业中都占有重要的地位，对环氧化反应的研究一直是有机化学的一个重要课题。 以反应介质和主催化元素为线索，对双氧水为氧源的烯烃环氧化反应的最新研究进展进行了综述。绿色化学的兴起使得以双氧水为氧源的环氧化反应引人注目, 从而成为近年来一个新的研究热点。双氧水作为环氧化试剂的突出好处是, 价廉易得, 活性氧含量高, 反应后的副产物仅仅是水, 环保性好。我们利用廉价无毒的碳酸钠作碱、低浓度的双氧水作氧源在常温下来实现苄叉氰乙酸酯的环氧化反应。该方法是一种高效的、后处理方便、环境友好的化学过程，在合成这一类化合物上具有重要的实际应用价值。 关键词：双氧水 环氧化 苄叉氰乙酸酯 Abstract Epoxides are highly useful intermediates for the manufacture of a range of important commercial products. There is a strong need for the development of new epoxidation methods which employ safer oxidants and produce little waste. Based on the reaction medium and the elements in the catalysts, the recent progresses of epoxidation of alkenes with hydrogen peroxide have been reviewed. The employment of hydrogen peroxide is an attractive option both on environmental and economic grounds. It is cheap, readily available and gives water as the only byproduct. The employment of hydrogen peroxide is an attractive option both on environmental and economic grounds. It is cheap, readily available and gives water as the only byproduct. We developed a novel methodology for the epoxidation of benzylidene acetate cyanide by the catalysis of sodium carbonate. The method is endowed with several unique merits, namely, simple procedure, convenient aftertreatment, mild and environmentally friendly conditions, which may be practical for commercial process. Keywords：Hydrogen Peroxide；epoxidation；benzylidene acetate cyanide 目 录 摘要……………………………………………………………………………………………1 ABSTRACT ………………………………………………………………………………1 第一章 研究背景 …………………………………………………………………………1 第二章 环氧化反应 ………………………………………………………………………1 1.常规介质中的环氧化反应 …………………………………………………………………1 1.1 金属元素催化 …………………………………………………………………………1 1.1.1 含铝催化剂 ………………………………………………………………………1 1.1.2 含钙催化剂 ………………………………………………………………………2 1.1.3 含锰催化剂 ………………………………………………………………………3 1.1.4 含铼催化剂 ………………………………………………………………………3 1.1.5 含钨催化剂 ………………………………………………………………………4 1.1.6 含钼催化剂 ……………………………………