暨南大学12有机化学考研试题.docxVIP

2011 年招收攻读硕士学位研究生入学考试试题 (副题) ******************************************************************************************** 812 C  O  A  O  10 NH CH3 NHCCHCH3 CH3 1 C O  2 CH3  3 CH3 COOCH3 Cl CH3 4  5 6 9 3- -2- (E)-2 4-  -3- 7 4-  -3- -2- 8 3- 10 (2R,3R)-2,3- 23 1 10 1) 1- 5 2) 2 3  5 5  8 50 1  CH3O  H2SO4 2 3  CH3CH2CH2NH2 + CH3Br(excess) HI CH3CHCH2OCH3 excess CH3 O 4  N H  2CH2  CH COOC2H5 C2H5OH 5 6  N  CH3  O  KMnO4 H2SO4 CF3COOOH 7  CH3  O CH O  H2O,HCl heat OH 1)KHCO3,H2O CO2 8 OH 9  C6H5COCH3 + HC CMgBr  Et2O  HgSO4 H3O+ + Br2  H2SO4 10 N ROOR HBr 11 O 12 C6H5CCH3 + HN NO2 O Cl  Cl NaOH 13 COOCH3 O + 14 15 COOCH3 O CH3CH2NH2 + CH3 Br2 光照 16 17  O  O O  NH2NH2 NaOH CO NH + CH3CH2Br  KOH 18 CO 19  CH3CH2CH2CHCH2OH CH3  KMnO4 (1) SOCl2 H2SO4 (2) CH3CH2OH OH + H5IO6  HAc,H2O 20  OH O 21 CH3CCH3 + CH2O + HN(CH3)2 HCl CH3OH CH CH2 CH2I2,Zn(Cu) Et2O 22 (1)CO2 N (2) H3O+ 23 K  OH HO3S N2+ + 24 OCH2CH CHCH3 25 20 1 A H 10 A C5H6O3  A  55cm-1,1820cm-1 CH3ONa/CH3OH  1  H NMR  B B 1 3H 13 1H B SOCl2 C C IR 1735cm-1,1785cm-1, C H2/Pd-BaSO4 D D IR cm-1,1740cm-1 A B C D 1 H NMR 12 1.CH3CHO  2CH3OH H+ O OCH3 CH3CH OCH3 2. CH3CH2CH2CNH2 Br2,NaOH, H2O CH3CH2CH2NH2 35 OH 1 CH3CH2CH2CH2Br CH3CH2CH2CH2CH2CCH3 (8分) CH3 Br NH2 2  O NO2 CH2  Br CN (9分) 3 CH3CCH3 4 CH3CH2CH2CHO  O  HN （9分） CH2 (9分) H NMR H NMR