暨南大学18有机化学考研试题.docxVIP

2011 年招收攻读硕士学位研究生入学考试试题（A 卷） ******************************************************************************************** 818  /  /  B 1.  C7H16  10  2  20 2. (E)-3, 4- -3- 3. R-2- 4. 6. -1- -4- CH2CH2NHCH3 5. 7. -  H2NCH2COOH 8.  HC C  CH3 H CH(CH3)2  9.  N  NO2 NH2 OH 10.  HO HO O OH OCH3 1.  ( )  15  2  30 A. C6H5CO- B. –CH2COOH C. –CH=CH2 D. –OCH3 2. A. CH3CH=CHCH2CH3 C. CH2=CH-CH2CH3 ( ) B. CH2=CHC≡CH D. C6H5CH3 3. 240? , ( ) A. 1 B. 2 C. 3 D. 4 4. ( ) A. C. 5. A. C. 6. - SN2  ( )  ( ) B. D. B. D. A. B. C. D.  NaOH  , 7. ( )  O  OH A. CHO B. H C. 8.  O  H OCH3  (  )  D.  CH3CHCOOH OH A. CH3COCH2COOC2H5 C. CH3COCH2COCH3 9. B. CH3COCH2CH3 D. CH2(CO2C2H5)2 A. C.   B. D.   10. A. B. C.  , ( ) D. NaOH , 11. CO2 ( ) A. 12. A. 13. A. 14. A. 15. A. B. B. B. B. B. C. C. C. C. C.  ( 19  ) (  ) D. D.??-D- D. ( ) D. D. 2  50  (  ) h? 1. 2. CH2CH3 + OH Br2 H2SO4 3.  O  CH3  +  CH3OH  H+ CH3 4. 5.  HO + HBr NH2  NaNO2/HCl OH  OH 6. CH3CH2CH2CHO Br  KOH/EtOH  KMnO4 7.  CH3 H+ 8.  Br  CH2Br  1. CN- 2. H3O+  SOCl2 9. CH3CH=CHCHO O 10. CHO  HOCH2CH2OH NaOH  OsO4 H3C  CH3  1. O3 11.  H CH3 CH3 2. Zn/H2O H2SO4 12. 13.  O  +  NH2  H+ -H2O H3CO  CHO  Ag2O  HCl/H2O 14. HO 15.  CO2Et CO2Et  +  O  NH2 NH2  1. EtONa 2. H2O NaOH 16.  N  CH3 + PhCHO 17.  H H CH3 Ph CH3  CH3I  Ag2O N(CH3)2 NaOH  HCHO 18. CHO + HCHO NaOH OH O Al[OCH(CH3)2]3 19. 1.  3 +  30  10 2 400 ml 40 g 0.5 mol KMnO4 9.2 g 0.1 mol 1 2 3 3 hr  7.3 g 200 ml 2. 12  C13H20N2O2 IR 1700 cm-1 NMR ? (ppm) 1.5 ( ( 3.  8 , 6H), 2.6 ( , 4H)  A , 4H), 2.75 ( , 2H), 4.2 ( NMR B , 2H), 4.35 ( ? 4.2 ppm , 2H), 6.5-7.8 Cl MeO MeO OBn  O  CO3H MeO MeO OBn H O  O MeO H  MeO 4 A  20 B 1. 2.  4 4  H  OH H CH2CH3 , CH3  , H3C O  O  CH2CH2CH3 CH3 3. (6  ) O O 4. 6 tosufluoxacin  O  COOH  6-  -2-  CH(OC2H5)3 H3C  N  N C2H5 To