金属有时行机化学.ppt

Organometallics金属有机化学 1. Introduction（引论） 1.1 Historical Development and Current Trends in Organometallic Chemistry (在金属有机化学领域的历史发展和当前趋势) 1760 The cradle(摇篮) of organometallic chemistry is a Paris military pharmacy(制药厂). It is there Cadet(军校学员) works on sympathetic inks（隐显墨水）based on cobalt salts. For their preparation, cobalt mineral which contain arsenic(砷) was used. As2O3 + 4CH3COOK --- “Cadet’s Fuming(发烟的) liquid” Contains cacodyloxide(卡可基氧) [(CH3)2As]2O (maldorous 恶臭的） First organometallic compound(化合物). 1827 Zeise’s salt Na[PtCl3C2H4] First olefin(烯烃) complex(络合物、配合物) 1840 R.