海洋沉积物中砷和汞联测方法的探讨.PDFVIP

中国农学通报 2012,28(29): 157-160 Chinese Agricultural Science Bulletin 海洋沉积物中砷和汞联测方法的探讨 陈财珍，吴成业 （福建省水产研究所，福建厦门361012） 摘 要：为了提高检测效率，采用微波消解-原子荧光法研究海洋沉积物中砷和汞的联测技术，通过实验 优化仪器参数和微波消解体系，以15 g/L 硼氢化钾为还原剂，用200 g/L 氨基磺酸溶液消除亚硝酸根 - (NO )对测定的干扰。结果表明，此方法对砷和汞标准曲线的线性回归系数均在0.999 以上，砷和汞的 2 检测限分别为0.02 mg/kg 和0.002 mg/kg ，相对标准偏差分别为2.63%和2.84% 。本方法具有操作简便、 快速、准确性高等优点，可用于同时检测海洋沉积物中砷和汞。 关键词：海洋沉积物；原子荧光法；联测；砷和汞 中图分类号：S912 文献标志码：A 论文编号：2012-1814 Investigation of Simultaneous Determination of Arsenic and Mercury in Marine Sediments ChenCaizhen,WuChengye (FujianFisheriesResearchInstitute,XiamenFujian361012) Abstract: Topromoteimprovementofdetectionefficiency,themethodwasinvestigatedforthesimultaneous determinationofarsenicandmercuryinmarinesedimentswithmicrowavedigestionbyatomicfluorescence spectrometry.Theinfluenceofinstrumentparametersanddigestivesystemwereoptimized. 15g/LKBH was 4 - selectedasreducingagent.TheinfluenceofNO wasavoidedby 200 g/Lamido-sulfonicacid.Theresults2 showedthat,twoelementsexhibitedgoodlinearityandtheregressioncoefficientswereallover 0.999.The developedmethodshowedlimitsofdetectionof0.02 mg/kgforarsenic,0.002 mg/kgformercuryandrelative deviatiaons of 2.63% for arsenic, 2.84% for mercury. The improved method, its simplicity, rapidity and accuracyhadgoodsuitabilityforthesimultaneousdeterminationofarsenicandmercuryinmarinesediments. Key words: marinesediments;atomicfluorescencespectrometry;simultaneousdetermination;ar