煤油超音速火焰热喷涂纳米WC-10Co4Cr涂层微观组织与宏观性能研究.DOCVIP

小浪底转轮氧-煤油超音速火焰热喷涂纳米WC-10Co4Cr涂层微观组织与宏观性能研究 刘焕虎 于跃 万永发 何瑞龙 李亚洲 刘钢钢 康聪芳 任海洲 （水利部小浪底水利枢纽管理中心，河南 济源 454681 ） 摘 要：小浪底转轮叶片采用不锈钢板材，是国内较早开展碳化钨防护的水轮机组，针对碳化钨的涂层剥落，作者也在探索一种更加有效的保护工艺和配方。本实验采用氧-煤油超音速火焰喷涂技术（HVOF）分别制备了微米结构、纳米结构WC-10Co4Cr涂层。通过扫描电子显微镜（SEM）分析了不同结构WC-10Co4Cr粉末和涂层的微观组织结构，并对涂层的显微硬度、结合强度、抗磨蚀性能进行了对比，探讨了涂层泥沙磨蚀机理。结果表明：HVOF制备的纳米结构 WC-10Co4Cr涂层组织致密，涂层的显微硬度、结合强度高于微米涂层，磨蚀失重也小于微米涂层；纳米结构细化了涂层晶粒，增强了涂层的显微硬度和韧性，提高了涂层的抗微切削和抗疲劳剥落性能，有利于涂层的抗泥沙磨蚀性能。 关键词：小浪底转轮；超音速火焰喷涂；WC-10Co4Cr；微米结构涂层；纳米结构涂层；泥沙磨蚀 中图分类号：TV698 文献标识码：A Xiaolangdi-runner Microstructure and Properties Research of Nanostructured WC-10Co4Cr Coating Sprayed by HVOF Abstract: Xiaolangdi-runner blades are made of stainless steel plates. They are the earlier hydropower units for tungsten carbide protection in China. The author is also exploring a more effective protection process and formulation for the coating peeling of tungsten carbide. In this experiment, the micro-structure and nanostructure WC-10Co4Cr coatings were prepared by oxygen-kerosene high velocity oxygen fuel (HVOF). The microstructures of WC-10Co4Cr powders and coatings with different structures were analyzed by scanning electron microscopy (SEM). The microhardness, bonding strength and abrasion resistance of the coatings were compared. The mechanism of coating sand erosion was discussed. The results show that the nanostructured WC-10Co4Cr coating prepared by HVOF is dense, the microhardness and bonding strength of the coating are higher than that of the micron coating, and the abrasion weight loss is smaller than that of the micro coating. The nanostructure refines the coating grain and enhances The microhardness and toughness of the coating improve the micro-cutting and fatigue-resistant peeling properties of the coating, which is beneficial to the anti-sand abrasion performance of the coating. Key words: Xiaolangdi-runner; HVOF; WC-10Co4Cr; Microstructure coating; Nano-structured coating; slurry erosion 作者简介：刘焕虎，男，（1984年6月~），山东聊城人，工学硕士，工程