聚丙烯碳基纳米复合材料微尺度流变实验研究-动力工程及工程热物理专业论文.docxVIP

优秀毕业论文 精品参考文献资料 小于大尺寸口模中的黏度。以不同口模中所对应的熔体黏度偏差百分比 小于大尺寸口模中的黏度。以不同口模中所对应的熔体黏度偏差百分比 表征黏度尺度效应的强弱。三种复合材料均随纳米粒子含量的增加黏度 尺度效应有减小的趋势，提高熔体温度则会导致材料的黏度尺度效应的 增强而剪切作用加强则会弱化黏度尺度效应。此外，对三种材料壁面滑 移研究发现复合材料在流道中的滑移速度与纳米颗粒、应力水平以及温 度相关。 采用间接法利用复合材料的PVT数据和黏流活化能得到了材料的黏 度压力敏感性系数。三种复合材料的压力系数则随着粒子含量的增加而 逐渐减小的趋势。此外从理论分析和计算公式来看温度升高会增大材料 的黏度压力敏感性系数，而升高压力则会减小该系数。 关键词：聚丙烯碳基纳米复合材料，黏弹性，黏度尺度效应，壁面滑 移，黏度压力敏感性 Ⅱ 万方数据 AbstractTHE Abstract THE RHEoLoGICAL PROPERTIES oF PoLYPRoPYLENE／CARBoN—BASED NANoCOMPoSITE S IN MICRoSCALE CHANNELS ABSTRACT With the development of polymer micro forming technology changed rapidly,the research of polymer flow properties under the microscale channels has become an important direction of polymer processing rheology．In micro。 channels，the melt has large SVR(surface volume ratio)as well as high pressure and shear rates．The micro—scale rheology research focused on the scale effect of viscosity and wall slip，pressure sensitivity of viscosity，etc． However，at present，a lot of research referring to microscale rheology only take the common pure polymer as obj ective，few study about the rheological properties of polymer nanocomposites in microcale channels has been reported．As a result，carbon nanotubes(CNT)，carbon black(CB)and graphite piece(GNP)filled polypropylene(PP)composites were prepared by melt blending，its viscoelasticity,multi—scale flow channel size dependence of viscosity and pressure sensitivity of viscosity based on PVT(pressure。 volume-temperature)datas were investigated in this paper． Dynamic rheological parameters including storage modulus，loss modulus and complex viscosity of the three nanocomposites were measured by using rotation rheometer under a condition of 1％strain．The result show IlI 万方数据 万方数据 万方数据 北京化工大学硕士学位论文that both 北京化工大学硕士学位论文 that both the modulus and viscosity increased with the n anoparticles content increasing，they also show a strong dependency on scanning frequency at low frequency area．The modulus of all three nanocomposites will be larger t