水-异丙醚-对苯二酚液-液-固等温平衡数据的试验测定.PDFVIP

20 1 No.1 Vol.20 2006 2 Journal of Chemical Engineering of Chinese Universities Feb. 2006 1003-9015(2006)01-0130-04 , ( , 215500) --50 46 -- 0.7~1.3 -- O642.42 O625.312 A Measurement of Isothermal Equilibrium Data of the Water-Diisopropylether-Hydroquinone System XU Hua, JU Hong-fang (Department of Chemistry, Changshu Institute of Technology, Changshu 215500, China) Abstract: For the water-diisopropylether-hydroquinone system, the isothermal equilibria, especially the isothermal equilibrium data at 323 K and 319 K were measured by gas chromatography respectively. There exist two liquid regions in these isothermal sections. One is the equilibrium region of a single liquid phase with solid hydroquinone. Another is a broad region of two partially miscible liquids. The experimental results show that it does not exist triple point of liquid-liquid-solid in the above isothermal regions. The experimental data measured include the saturated solubility of hydroquinone and compositions of two co-existing liquid phases. The distributive coefficients are about 0.7~1.3 for the extraction of hydroquinone from water with diisopropyl ether, which are much less than those for the extraction of phenol from water with the same extractant. The results show that it is inefficient to use diisopropyl ether as extractant to extract hydroquinone from water isothermally. Key words: ternary phase diagram; isothermal eguilibrium data; diisopropyl ether; hydroquinone; liquid-liquid-solid equilibrium 1 ( )--1980 [1](CA) 1976 4 [2~5]-- 68 50