熔盐电解制备金属钒-钢铁钒钛.PDFVIP

第33卷第1期 钢摇 铁摇 钒摇 钛 Vol.33,No.1 2012年2月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 February2012 熔盐电解制备金属钒 王淑兰,李世超,顾东燕 (东北大学理学院化学系,辽宁沈阳110004) 摘摇 要:以氧化物为原料,采用熔盐电解的方法,制备了金属钒。 研究了电解温度、电解电压、电解时间和阳极面积 等参数对电解电流的影响规律。 用扫描电镜、微区分析和X-射线表征了未完全还原及完全还原的试样的形貌、结 构和组成。 在850~900 益温度范围、2.9~3.0 V 电压范围实验室规模上电解获得了金属钒。 该方法具有温度低、 流程短、设备简单,适合小规模化生产的优点。 关键词:金属钒;熔盐电解;电解电流 中图分类号:TF841郾3摇 摇 文献标识码:A摇 摇 文章编号:1004-7638(2012)01-20-04 Preparation of Vanadium Metal by Molten Salt Electrolysis Wang Shulan,Li Shichao,Gu Dongyan (College of Sciences,Northeastern University,Shenyang 110004,Liaoning,China) Abstract:Vanadium metal was prepared by molten salt electrolysismethod using vanadium oxide asraw material. Theinfluenceof electrolysisparameterssuchaselectrolysistemperature,electrolysisvoltage,e鄄 lectrolysis timeandtheareaof anodeonelectrolysiscurrentwasstudied. Scanningelectromicroscopeim鄄 age,microanalysis and X-ray diffraction were used to characterize the composition,structure and mor鄄 phology of specimens which were incompletely and completely reduced. Vanadium was obtained in the lab-scale production under the temperature of850~900 益 andvoltage of2.9~3.0 V. Dueto itsshort processflow andlow temperature and simple equipment requirements,thismethod exhibitsadvantagesin small scale production of vanadium. Key words:vanadium metal;molten salt electrolysis;electrolysis current 域,会出现三个新的钒需求渠道,即钒化合物作为锂 0摇 引言 离子电池的阴极材料、V O 作为钒电池的储能介质 2 5 摇 摇 钒除了在钢铁工业中作为合金元素的应用不断 及钒提高稀土磁铁在较宽的温度和湿度范围内的耐