sno2纳米材料的制备及气敏性能研究微电子学与固体电子学专业论文.docxVIP

5n02纳米材料的制备及气敏性能研究一般Sn02纳米材料及本文中的Sn02纳米空心球，主要原因是该材料暴露的{1l 5n02纳米材料的制备及气敏性能研究 一般Sn02纳米材料及本文中的Sn02纳米空心球，主要原因是该材料暴露的{1l 1) 晶面具有很高的催化活性，有助于氧化还原反应的快速进行。 采用水热法合成暴露{332}高指数晶面的Sn02正八面体，Sn02{332}JE／＼面 体棱长为95nm，两顶点间距离为140nm，在最佳工作温度250。C下，对800ppm 乙醇气体的灵敏度达2200，约为Sn02{111)最大灵敏度的12倍，且最佳工作温 度低于Sn02{111)，响应恢复时间分别为1．5s和32s，气敏性能优于Sn02{111) 八面体材料，原因是f332}晶面的催化活性高于{111)晶面，反应速率更快且最佳 工作温度降低。 关键词：空心球；高指数晶面；气敏性能 万方数据 厦门大学硕士学位论文 厦门大学硕士学位论文 Abstract Abstract As the science and technology of modem society develop rapidly,living standards improves，at the same time，environmental pollution is also becoming more and more serious，including gas pollution．Thus gas sensors are used to monitor the environment gas and sound the alarm in time，which Can effectively solve the gas pollution problem．In a variety of gas sensors，the gas sensor of metal oxide semiconductor has high sensitivity,low cost，long life and other advantages． Combining with the nanotechnology further improve the performance of gas sensitive． Sn02 nano material is one of the most common used gas sensitive substrate materials， but in practical application there are still some shortcomings，like poor selectivity and 11igh working temperature．Thus for the sake of further improving the gas sensor applications of nano Sn02 materials，reducing size of materials，doping and some other methods are used．Among these methods，changing the microstructures Can effectively increase the specific surface area，then increase the amount of target gas． Regulating the exposed high energy facets Can improve the surface reactivity of material，thus improve the reaction rate．In this study,two methods of changing the microstructures and regulating the exposed high energy facets to improve the performance of gas sensitive have been investigated．The connections between gas sensing and microstructure and crystal activity have also been explained． One step hy