现代材料学教案3-Functional polymer.pptVIP

现代材料学--高分子材料 功能高分子材料 History of Conducting Polymers The 1970’s brought research in the area of polymers Alan MacDiarmid along with Hideki Shirakawa and Alan Heeger discovered metallic properties in an organic polymer Common growth techniques Templateless GrowthTime/Voltage Dependence Templateless GrowthTime/current dependence Templateless GrowthAdvantages and uses Templateless GrowthApplications and Advantages of molecular alignment Applications of oriented electroactive polymers 蓮花效應(Lotus Effect) 在超高解析度電子顯微鏡下可以清晰看到： 在荷葉葉面上佈滿著一個挨一個隆起的“小山包” 在山包上面長滿絨毛 在“山包”頂則又長出 一個個饅頭狀的 “碉堡”凸頂。 Micro- and nanostructured plant surfaces 蓮葉的表面(cultiule)具有大小約 5~15 ?m細微突起的表皮細胞(epidermal cell)， 表皮細胞上又覆蓋著一層直徑約1nm的蠟質結晶(wax crystal)。 蠟質結晶本身的化學結構具有疏水性。 表面細微的奈米結構在自潔功能上扮演著關鍵的角色 以蓮葉為例，水珠與葉面接觸的面積大約只佔總面積的2～3%， 若將葉面傾斜，則水珠被迫以滾動方式運動。 滾動時，會順便吸附起葉面上的污泥顆粒，一同滾出葉面 達到清潔的效果。 Requirements for Interface Applications Mechanical stabilization Control temperature Transpiration gas exchange Self-cleaning effect:D:\2003-2-26\中正物理所-奈米科技課程\Lotus Effect\Droplet in smooth surface.exeD:\2003-2-26\中正物理所-奈米科技課程\Lotus Effect\Cleaning demo for lotus effect surface.exe Lotus Effect on various surfaces Lotus-effect Applications in BASF Aerosol spray combines nanoparticles with hydrophobic polymers such as polypropylene, polyethylene and waxes. It also includes a propellant gas. As it dries, the coating develops a nanostructure through self-assembly. The spray particularly suits rough surfaces such as paper, leather, textiles (紡織) and masonry (磚瓦) The self-cleaning shoe may soon be a reality. The current situation The spray may affect the color of dark surfaces as its layers are slightly opaque. The coating can also be mechanically unstable on smooth surfaces. But BASF is working to overcome these problems. The company even aims to develop a product that will retain its lotus effect after abrasion with sandpaper. Dubbed lotus stone, the material has potential for use in the construction industry, i