助熔剂对Eu2掺杂的碱土金属硅酸盐荧光粉发光性能的-硅酸盐学报.PDFVIP

· 206 · 硅 酸 盐 学 报 2010 年 第38 卷第2 期 硅 酸 盐 学 报 Vol. 38 ，No. 2 2 0 1 0 年 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY February ，2010 助熔剂对Eu2+掺杂的碱土金属硅酸盐荧光粉发光性能的影响 张希艳，张亮亮，张云鹏，董 飞，于冲冲 (长春理工大学材料科学与工程学院，长春 130022) 摘 要：研究了不同助熔剂对Eu2+掺杂的MgO·2SrO·SiO2 发光性能的影响。结果表明：加入3%(质量分数)BaF2 作为助熔剂时样品发光效果最好。对 400 nm 紫外光激发下样品的发射光谱进行了Gauss 拟合，出现了3 个发光中心。采用van Uitert 提出的Eu2+5d 激发态带边位置与配位数的经验公式进 行计算，认为3 个发光中心是由Eu2+分别取代Sr( Ⅰ)格位、Sr( Ⅰ)格位附近形成的杂质束缚激子态和 Sr( Ⅱ)格位形成的。晶体场强度与X—O 键长成 反比，随着掺入助熔剂阳离子半径的增大，发射光谱发生了红移。 关键词：助熔剂；碱土金属硅酸盐；荧光粉；Gauss 拟合 中图分类号：O482 31 文献标志码：A 文章编号：0454–5648(2010)02–0206–05 EFFECTS OF DIFFERENT FLUXING AGENTS ON THE LUMINESCENT PROPERTIES OF 2+ Eu -DOPED ALKALINE EARTH SILICATE PHOSPHORS ZHANG Xiyan ，ZHANG Liangliang ，ZHANG Yunpeng ，DONG Fei ，YU Chongchong (School of Material Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China) Abstract: Effects of different fluxing agents on the luminescent properties of Eu2+-doped MgO·2SrO·SiO phosphors were studied. 2 The results indicate that the sample with 3% in mass BaF2 as fluxing agent has the best luminescence property. The emission spectrum excited by 400 nm ultraviolet light was evaluated by Gaussian fitting. There are three luminescent centers in the spectrum. According to the calculated result with the empirical formula proposed by van Uitert, the three luminescent centers can be originated from the substitution of Eu2+ ions for Sr ( Ⅰ) lattice sites, the impurity-bound exiton states near the Sr ( Ⅰ) sites and Sr ( Ⅱ) sites, respectively. Since the cry