纳米SiC对高频脉冲电沉积Ni镀层性能的影响-表面技术.PDF

第 45 卷 第 12 期 表面技术 2016 年 12 月 SURFACE TECHNOLOGY ·91 · 纳米 SiC 对高频脉冲电沉积 Ni 镀层性能的影响 刘演龙 （海装重庆军代局，重庆 400042） 摘 要：目的研究纳米SiC 颗粒对Ni 镀层的摩擦性能、显微硬度等的影响。方法 采用高频脉冲电沉 积技术制备了Ni/ 纳米SiC 复合镀层，通过调整占空比实现了纳米SiC 颗粒呈梯度分布。采用拉伸法测 量了镀层的结合强度。通过摩擦磨损试验研究了Ni/ 纳米SiC 复合镀层的摩擦系数和耐磨性能。采用纳 米压痕测量了梯度镀层截面显微硬度和弹性模量的分布。结果 纳米SiC 颗粒呈梯度分布的镀层的结合 强度超过40 MPa ，而非梯度的仅为19 MPa。含质量分数为1.5%纳米SiC 颗粒的镀层的摩擦系数约为 0.26 ，而纯镍镀层的约为0.40 ，且含纳米SiC 颗粒的镀层的磨痕宽度小且浅。纳米SiC 颗粒呈梯度分布 的复合镀层的表层显微硬度为6.0 GPa ，弹性模量为250 GPa ，而靠近界面处的显微硬度为1.9 GPa，弹 性模量为160 GPa。结论 纳米SiC 颗粒呈梯度分布的镍镀层的结合强度明显高于非梯度镀层的。随纳 米 SiC 颗粒含量的增加，镍镀层的耐磨性能增加，摩擦系数降低，且纳米压痕显微硬度和弹性模量也 相应的增加。 关键词：纳米SiC 颗粒；镍基复合镀层；梯度镀层；结合强度；摩擦系数；显微硬度；弹性模量 中图分类号：TG174.442 文献标识码：A 文章编号：1001-3660(2016)12-0091-06 DOI ：10.16490/j.cnki.issn.1001-3660.2016.12.015 Effect of Nano-particle SiC on the Properties of Ni Coating Fabricated by High Frequency Pulse Electrodeposition LIU Yan-long （Representative Bureau of Naval Equipment Department in Chongqing, Chongqing 400042, China ） ABSTRACT: Effect of nano-particle SiC on the frictional behavior ，and microhardness etc of Ni coatings were researched. Ni/nano-SiC composite coatings were prepared by high frequency pulse electrodeposition, and the NiS/nano-SiC gradient com- posite coatings were obtained by changing duty cycles; The bond strength of Ni/nano-SiC composite coatings was measured by tensile test; The friction coefficient and wear-resisting property were investigated by friction and wear test; The distributing of microhardness and E in cross-section of Ni/nano-SiC gradient composite coatings were estimated by nanoindentaion. The bond strength of Ni/nano-SiC gradient composit