硫化物矿山尾矿缓释抑菌剂滴丸的制备及性能测试-北京玛格泰克科技.PDF

中国环境科学 2012,32(6) ：1087~1092 China Environmental Science 硫化物矿山尾矿缓释抑菌剂滴丸的制备及性能测试 * 张 哲,杨 琛 ,党 志,舒小华 (华南理工大学环境科学与工程学院,工业聚集区污染控制与生态修复教育部 重点实验室,污染控制与生态修复广东省教育厅重点实验室,广东 广州 510006) 摘要：为阻止或减缓嗜酸性硫氧化菌对硫化矿物的氧化,研究了十二烷基磺酸钠(SDS)对广东韶关大宝山多金属尾矿区分离出的氧化亚铁 硫杆菌的杀菌效果.为提高抑菌剂的有效利用率,采用滴制法将其制备成具有缓释功能的抑菌剂滴丸,并分析了抑菌剂滴丸的表面特征、元 素组成及缓释性能.结果发现:滴制法可以把 SDS 均匀地分散在以醋酸纤维素为骨架的缓释滴丸内部;滴丸的载药率可以达到 40% 以上;实 验周期内杀菌成分可在酸性溶液中持续缓慢溶出,溶液中 ρ (SDS)逐渐升高.氧化亚铁硫杆菌摇瓶浸矿结果显示:使用抑菌剂缓释滴丸后,实 验周期内溶液的 pH 值、Eh 变化幅度较小,而且 Zn2+ 、总Fe 的溶出率分别比未加滴丸的处理低61.37%、84.44%,缓释杀菌作用显著. 关键词：硫化物矿山尾矿；酸性矿山废水；氧化亚铁硫杆菌；缓释杀菌 中图分类号：X172 文献标识码：A 文章编号：1000-6923(2012)06-1087-06 * Preparation and performance testing of bactericide sustained-release capsules. ZHANG Zhe, YANG Chen , DANG Zhi, SHU Xiao-hua (Key Laboratory of Guangdong Province for Pollution Control and Ecological Restoration, Key Laboratory for Industry Clusters Pollution Control and Ecological Restoration, Ministry of Education, College of Environmental Science and Engineering, South China University of Technology Guangzhou 510006, China). China Environmental Science, 2012,32(6)：1087~1092 Abstract ：The oxidation of sulfide tailings could lead to acid mine drainage (AMD) and heavy metal pollution problems in the mining area, it was important to prevent the oxidation of sulfide tailing to control the pollution of mining. Previous researches revealed that acidophilic bacteria, represented by Acidthiobacillus ferrooxidans (A.f), played a key role in the process of oxidation of minerals. The aim of this study was to inhibit the biooxidation of sulfide tailing through bactericidal sustained-release capsu