热处理气氛对碱化处理Ti-6Al-4V表面性质之影响.DOC

熱處理氣氛對鹼化處理Ti-6Al-4V表面性質之影響 The effects of heat treatment atmosphere conditions on the alkali-modified Ti-6Al-4V surface properties 研究生：黃信銘 Huang, Hsin-Ming 指導教授：洪廷甫 Honng, Ting-Fu 【摘要】 本研究主要探討經5 M、10 M NaOH鹼化處理與去離子水處理後之Ti-6Al-4V試片分別經由600°C大氣及真空熱處理條件下，所形成鈦酸鈉水凝膠層並分別進行結晶相結構、表面形貌、成份分析、表面粗糙度、親疏水性及機械性質等分析，並浸泡於人工模擬體液(Simulated Body Fluid, SBF)，來觀察鈦合金試片表面形成類骨質層之差異性。本研究所使用人工模擬體液為(Modified SBF, m-SBF)，浸泡時間為1~28天，並對試片表面所生成之類骨質層來加以進行分析與探討。 實驗結果得到5 M、10 M 鹼化處理皆可將鈦合金試件表面生物活性化，經由大氣熱處理後皆有效提升鈦酸鈉水凝膠層與基材之附著強度、彈性係數等機械性質。5 M、10 M NaOH鹼化去離子水處理後於600°C大氣及真空熱處理，並浸泡於m-SBF中皆可在第5天內生成類骨質層。NaOH鹼熱處理後並浸泡於m-SBF 1~28天，進行奈米壓痕試驗由實驗結果可得到，大氣熱處理能提高試片表面被覆層之機械性質，但真空熱處理後試片表面因缺乏氧原子擴散反應，使得機械性質方面表現不如大氣熱處理來的出色。 關鍵字: Ti-6Al-4V、鹼熱處理、人工模擬體液、類骨質、奈米壓痕、附著強度 【Abstract】 The purpose of this study is to investigate the bone-like apatite inducement ability on the 5, 10 NaOH, deionized water (D.I. water) and 600°C atmospheric and the vacuum heat treated Ti-6Al-4V surfaces. All the generated sodium titanate surfaces of samples were characterized their crystallographic structure, morphology, chemical composition, surface roughness, contact angle measurement and mechanical properties, respectively. Ti-6Al-4V surfaces in the simulated body fluid (SBF) solutions, monitoring the mobility changes of the bone-like apatite layer formation process on Ti-6Al-4V specimen surfaces. The treated specimens were soaked in m-SBF for 1~28 days for bioactivity evaluation. The results showed that 5M and 10M alkali treatments can successfully bioactivate the Ti-6Al-4V specimen surfaces. The specimen with following heat treatment at 600°C even had crystallinity intensity of generated sodium titanate and elastic constants. After soaking in the m-SBF, a thin bone-like apatite layer was formed along the heat treated Ti-6Al-4V surfaces with in 5 days. The treated specimens followed by NaOH were soaked in m-SBF for 1~28 days for Nano-indentation test. The experimental results show that specimen surfaces mechanical properties are promoted when atm