一种阻燃环氧树脂复合材料性能研究Performancestudyon.pdf

一种阻燃环氧树脂复合材料性能研究 Performance study on the flame retardant self-adhesive resin composites 乌云其其格 （中航复合材料有限责任公司，北京，100095） Wuyunqiqige (AVIC Composite Corporation LTD, Beijing,101300,China) 摘要：用热熔共混法制备一种增韧阻燃改性的 125/1h 固化的树脂体系。该树脂的增韧改性考虑了树脂的耐热性，改性后的树脂固化物的玻 璃化转变温度为 145℃，阻燃改性时考虑了无卤阻燃，确定固化工艺时保证力学性能的前提下考虑了低的固化温度和短的固化周期。本文中 对树脂的粘度-温度曲线、凝胶时间-温度曲线、DSC 进行分析，确定了树脂的固化工艺。采用热熔胶膜法制备玻璃布、和碳布预浸料；采用 模压法制备层压板，采用真空袋法制备滚筒剥离强度试样；对预浸料和复合材料进行物理性能和力学性能测试，对比预浸料蜂窝夹层结构 的滚筒剥离强度，结果表明，树脂预浸料自粘性较好，夹层结构的滚筒剥离强度高，满足应用指标要求，制备夹层结构时预浸料可以直接 粘接蜂窝芯材，比起使用胶膜粘接芯材和蒙皮制备夹层结构，简化了工艺，并减轻结构重量。对玻璃布预浸料复合材料层压板进行垂直燃 烧、烟密度和氧指数的测定，结果表明，玻璃布复合材料的燃烧性能较好，可以用于具有阻燃要求的复合材料结构件。 关键词：阻燃；树脂；复合材料；性能；自粘性 Abstract: The toughening and flame retardant modification resin system cured in the time of 125/1 h is prepared by melt blending method. The heat resistance of resin is considerd for the resin toughening modification, and the glass transition temperature of the modified resin cast has been changed as 145 ℃. The flame retardant is improved by combine no halogen flame retardant and a small amount of bromine flame retardant, and the low curing temperature and curing cycle short are taken into account in the determination of the curing process under the premise of good mechanical performance. This article analysis the resin viscosity-temperature curves, glue solidified time-temperature curves and DSC, and the resin curing process is determined. The glass cloth, carbon cloth and aramid presoak cloth material, laminate and drum peel strength specimens are prepared by the hot melt adhesive film, compression molding and vacuum bag samples, respectively. The physical properties and mechanical properties of the presoak material and composite material are tested, the results show that the resin pr