控制还原法制备高性能MnONi锂离子电池负极材料-硅酸盐学报.PDF

第45 卷第7 期 硅 酸 盐 学 报 Vol. 45 ，No. 7 2 0 1 7 年 7 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY July ，2017 DOI ：10.14062/j.issn.0454-5648.2017.07.02 控制还原法制备高性能MnO@Ni 锂离子电池负极材料 孙永辉，高 强，范小明，田 院，杨则恒，张卫新 (合肥工业大学化学与化工学院，合肥 230009) 摘 要：以乙酸镍、乙酸锰为原料，碳酸氢钠为沉淀剂，利用共沉淀法制备了镍锰碳酸盐前驱体，并在还原气氛中通过控制 还原法制备了具有不同Mn/Ni 摩尔比的球形MnO@Ni 负极材料，并对其成分、形貌和元素分布及电化学性能进行表征。结 果表明：通过在MnO 体相中均匀掺入合适比例的高导电性金属镍，可以有效提高锂离子电池负极材料MnO 的电化学性能。 Mn/Ni 摩尔比为1:10 时，MnO@Ni 负极材料5C 放电比容量为214.3 mA·h/g ，0.5C 循环200 次容量保持率为72%，呈现出高 的倍率性能和循环保持率。 关键词：锂离子电池；共沉淀；控制还原；制备；一氧化锰；电化学性能 中图分类号：TM911 ；TQ152 文献标志码：A 文章编号：0454–5648(2017)07–0898–06 网络出版时间：2017–05–19 06:46:57 网络出版地址：/kcms/detail/11.2310.TQ0646.002.html Reduction-controlled Synthesis of High-performance MnO@Ni Anode Materials for Li-ion Batteries SUN Yonghui, GAO Qiang, FAN Xiaoming, TIAN Yuan, YANG Zeheng, ZHANG Weixin (School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China) Abstract: Nickel and manganese carbonate precursors were synthesized by a co-precipitation route with nickel acetate and manganese acetate as raw materials and sodium bicarbonate as a precipitant. Via controlled reduction of the precursors, the spherical MnO@Ni composite anode materials with different Mn/Ni molar ratios were prepared. The crystal structure, morphology and chemical composition as well as electrochemical performance of the samples were characterized. The results show that modification of impregnating metallic Ni in MnO materials can effectively improve the electrochemical performance of MnO anode materials for lithium ion batteries. The composite anode