石灰石和贝壳的煅烧及CO2吸收循环特性-中国电机工程学报.PDFVIP

第31 卷 第35 期 中 国 电 机 工 程 学 报 Vol.31 No.35 Dec.15, 2011 72 2011 年12 月15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 0258-8013 (2011) 35-0072-06 TK 224 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 石灰石和贝壳的煅烧及CO2 吸收循环特性 高英，陈汉平，杨海平，王贤华，张世红，汪军 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市430074) Kinetic and Cyclic Absorbing CO Characteristics of Limestone and Shell 2 GAO Ying, CHEN Hanping, YANG Haiping, WANG Xianhua, ZHANG Shihong, WANG Jun (State Key Laboratory of Coal Combustion (Huazhong University of Science and Technology), Wuhan 430074, Hubei Province, China) ABSTRACT: In the paper, natural limestone and shell were 低，通过多次循环后样品的孔径分布和扫描电镜形貌观察 chosen as calcium-based materials for calcination/carbonation 到，石灰石微孔减少，烧结现象严重，而贝壳分布在中孔和 cyclic reactions due to their low cost and rich resources. The 大孔之间，钙利用率较低，形貌未发生明显变化。由于二者 calcinations kinetic characteristics and CO2 adsorption 组分和结构上的差异，使得天然石灰石在 CO2 循环吸收性 characteristics of both materials were studied using thermo- 能上优于贝壳，而贝壳则具有较好的循环稳定性。 gravimetric analysis (TGA). Simultaneously, product was used 关键词：石灰石；贝壳；煅烧/碳酸化；循环 to investigate the particle size distribution and scanning electron microscopy (SEM) of products pre and post the cycle. 0 引言 The results show that the adsorption activities of both materials CO2 作为主要的温室气体，其收集和回收成了 decreases as the cycle number increases. From the particle size 目前大家关注的焦点。天然钙基材料通过煅烧/碳酸 distribution and SEM of samples after multiple cycles, it is 化可有效的实现CO2 脱除和吸