贵州瓮福磷矿石中碘的赋存状态及其提取工艺的研究-有色金属冶金专业论文.docxVIP

贵州大学硕士学位论文 贵州大学硕士学位论文 II II 时间 7 分钟；气液比是 150:1；吸收温度 35℃；二氧化硫流速 200ml/s；吸收塔 液气比 25：1。 在最佳工艺条件下，进行连续考查实验表明：碘的吹出率在 50%左右，碘的 吸收率约 81%。吹出和吸收系统设备的设计或选型基本符合要求，吹出率过低， 是由于黄磷废水体系复杂，例如 PH 值等指标不能改变，否则会影响生产。 关键词：碘赋存状态；碘；黄磷废水；半工业化试验 PAGE PAGE IV Researth on Occurrence of Iodine in Phosphate Rock in Guizhou Wengfu and Extraction Process Abstract Iodine is widely used in the industry, agriculture, national defense and other fields as a strategic material.China is an deficient iodine country, iodine more than 90% of total demand is imported from abroad.Guizhou phosphate ore is rich in iodine, studying occurrence of iodine will help us better understand geochemistry of the element iodine and migration of iodine. It HYPERLINK /dict_result.aspx?searchword=%e6%8f%90%e4%be%9b%e4%ba%86%e4%be%9d%e6%8d%aeamp;tjType=sentenceamp;styleamp;t=provide%2Btheoretical%2Bbasis provides theoretical basis for the comprehensive utilization of iodine and looking for mines. Yellow phosphorus wastewater can be recycled by closed-circuit treatment, and iodine from the raw phosphate rock is enriched in the water. Under the conditions of not effecting producing, we use semi-industrial device of self-design or selection to study process of iodine extraction . Various methods are used to study on the occurrence of iodine in this paper. x-ray diffraction and infrared analysis showed that the phosphate rock containing iodine apatite is mainly carbonate fluorapatite. Polarized light microscopy analysis showed that collophanite is the main mineral. It exists in the form of oval-shaped andintraclast in the ore. Chemical analysis shows the content of iodine increases with the increase of phosphorus pentoxide,so relation between iodine and phosphate rock are closely. x radio spectrometer detects elements which are composed of phosphate rock, quartz, dolomite and other mineral. Picking up singled minerals shows that the iodine content of phosphate rock is much larger than total iodine content of other single mine