丹江口水库沉积物重金属形态分布特征及其迁移能力.PDF

中国环境科学 2016,36(4) ：1207~1217 China Environmental Science 丹江口水库沉积物重金属形态分布特征及其迁移能力 * 李佳璐,姜 霞 ,王书航,王雯雯,陈俊伊 ( 中国环境科学研究院,环境基准与风险评估国家重点实验室,北京 100012) 摘要：以丹江口库区及其支流为研究对象,采用连续分级提取法研究了表层沉积物中 Cr、Ni 、Cu、Zn 、As 、Cd、Hg 和 Pb 各形态的空间 赋存特征和相对比例,探讨了各形态金属的稳定度并对其进行污染评价.结果表明,表层沉积物各形态金属分布都具有明显的空间差异性, 高值集中于库区中部、西部入库支流和丹江库区西北部.沉积物中 Pb 的可还原态、Cd 的弱酸提取态占总量的质量分数较高,分别达到 54.91%和 42.19%,其余重金属则以残渣态为主.重金属稳定度分析表明,8 种金属稳定性顺序为 CrPbAsNiCuHgZnCd,Cd 在大部分 点位处于不稳定状态,快速解吸释放的风险较大. 关键词：丹江口水库；沉积物；重金属；形态；稳定度；连续提取 中图分类号：X524 文献标识码：A 文章编号：1000-6923(2016)04-1207-11 * Heavy metal in sediment of Danjiangkou Reservoir: chemical speciation and mobility. LI Jia-lu, JIANG Xia , WANG Shu-hang, WANG Wen-wen, CHEN Jun-yi (State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China). China Environmental Science, 2016,36(4) ：1207~1217 Abstract ：BCR three stage sequential extraction procedure was applied to examine the spatial occurrence characteristics and relative ratio of the speciation of Cr, Ni, Cu, Zn, As, Cd, Hg and Pb in the sediments from Danjiangkou reservoir, and meanwhile their stability and pollution assessment were discussed. All types of metals had obvious spatial heterogeneity; their high value was grouped in the middle of the reservoir, the west of tributaries and the northwest of Danjiang reservoir. Most metals mainly existed in residue state except for Pb and Cd, the reducible Pb and acid soluble Cd respectively accounted for 54.91% and 42.19% of the total content. The stability of eight studied metals was in the order of CrPbAsNiCuHgZnCd. Cd was unstable in most studied sites