第7课-电子能量损失谱教学课件.ppt

* (A) Differences between the ELNES of the carbon-K edge from various forms of carbon. (B) Change in the Cu L2,3 edge ELNES as Cu metal is oxidized and the filled d states lose electrons, thus permitting the appearance of white lines. * The change in the ELNES of the Si L edge across an interface between crystalline Si and amorphous SiO2. Local electronic changes at the atomic level are easily discerned. * Appl. Phys. Lett. 90, 154101 (2007) * atomic positions and the atomic information comes from a relatively short range (the first few nearest neighbors) Fourier transforming * The EXELFS analysis of Pd30Ni50P20 bulk metallic glass. (A) The pre-edge, background-subtracted P K-edge. (B) The isolated w(k) data. (C) The Fourier transform of w(k) to radial space, FT[w(k)], and (D) the back-Fourier transform of the first peak of FT[w(k)] back to k-space (dots) and fitting with a calculated function for a tetragonal dodecahedron (dashed line). The model in the center is a tetragonal dodecahedron with a P atom at the center surrounded by a first nearest-neighbor shell of Pd and Ni atoms deduced from the EXELFS. * * It isn’t particularly apparent from the figure, but we’ll see later that the low-loss region contains electronic information from the more weakly bound conduction and valence-band electrons, while the high loss region contains primarily elemental information from the more tightly bound, core-shell electrons and also details about bonding and atomic distribution. * The post-column Gatan Image Filter (GIF) is a development of their magnetic-prism PEELS. The incolumn filter, a magnetic variant of the original Castaing- Henry magnetic prism/electrostatic mirror, is exemplified by the Omega (O) filter, pioneered by Zeiss and also now used by JEOL. The in-column filter, as the name implies, is integrated into the TEM and sits between the specimen and the viewing screen/detector (rather than being an optional addition, like the PEELS/ GIF). Magnetic spectrometers, alo