465-添加剂对冰浆性能影响实验研究.pdf

添加剂对冰浆性能影响实验研究 李成浩 孙志高 杨明明 陈之帆 （苏州科技大学环境科学与工程学院，江苏苏州 215009） 摘 要：选用液体石蜡为油相，通过加入少量表面活性剂和乙醇制备了乳液浆体。利用 混合量热法测量了乳液浆体含冰率与表面活性剂种类和添加量、乙醇添加量之间的关系。在 相同的相变结晶时间内，油酸质量分数的变化对含冰率影响很小。乙醇的添加降低了冰点和 含冰率，增大了过冷度，但可以防止冰浆粘附容器壁面，改善了流动性。当添加的油酸和乙 醇质量分数分别为 0.5wt%和 3wt%，环境温度为-8.5℃，相变结晶时间为 90min 时，制备的 乳液浆体含冰率达到 31.4%，表观粘度为 25.5mPa ·s，浆体不粘附壁面，冰颗粒分散均匀， 具有良好的流动性。 关键词：蓄冷；冰浆；表面活性剂；相变 Experimental Study on the Effect of Additives on the Performance of Slurry Li Chenghao Sun Zhigao Yang Mingming Zhang Aijun Wang Mao (School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China) Abstract: Paraffin liquid is chosen as oil phase to form emulsion for slurry producing with a small amount of surfactants and ethanol. The mixing calorimetry method is used to measure the ice packing factor (IPF) to evaluate the effect of the types and the amount of surfactants, the amount of ethanol on IPF. The IPF of emulsion slurry is almost not changing with the increase of oleic acid mass fraction under the same crystallization time in this work. IPF and the freezing point reduces and the degree of supercooling increases with the adding of ethanol, but it can prevent ice from adhering to the cooling surface and improve fluidity. The experimental results show that IPF and apparent viscosity are about 31.4% and 25.5mPa·s after 90min crystallization at -8.5℃ conditions when the mass fraction of oleic acid and ethanol in emulsion are 0.5wt% and 3wt%, respectively. The slurry does not adhere to the cooling surface and dispersed well. The slurry has a good fluidity. Keywords: Cold storage; Slurry; Surfactant; Phase change 基金项目：江苏省高校自然科学研究重大项目资助项目（16KJA480001）；江苏省住建厅科技项目(2016ZD134) 和江苏省研究生科研创新计划项目（KYCX17_2066） 联系人：孙志高，Tel:0512通讯地址: 215009 江苏省苏州市苏州科技大学环境科学与工程学 院 E-mail: szg.yzu@163.com。 1 前言