季铵型阳离子聚丙烯酰胺的无盐染色行为.docxVIP

季铵型阳离子聚丙烯酰胺的无盐染色行为腾晓旭，马 威，张淑芬（大连理工大学精细化工国家重点实验室，辽宁 大连 季铵型阳离子聚丙烯酰胺的无盐染色行为 腾晓旭，马 威，张淑芬 （大连理工大学精细化工国家重点实验室，辽宁 大连 116012） 摘 要：以季铵型阳离子聚丙烯酰胺作为一种新的阳离子助剂对棉纤维进行处理，应用于活性染料无盐染色，对 染色过程中染料与处理后棉纤维之间的吸附类型、吸附热力学及吸附动力学进行了研究。结果表明，无盐染色过 程符合 Langmuir 吸附模型；吸附过程是放热自发进行的，低温有利于染料的吸附；吸附动力学符合二级动力学模 型，属于化学吸附过程。与传统有盐染色结果相比，染色后的阳离子化棉纤维色深增加，染料利用率提高。 关键词：季铵型阳离子聚丙烯酰胺；棉纤维；活性染料；无盐染色 中图分类号：TQ 619.1 文献标识码：A 文章编号：1000–6613（2010）03–0563–06 Pretreatment of cotton by cationic polyacrylamide with quaternary ammonium group in salt-free dyeing TENG Xiaoxu，MA Wei，ZHANG Shufen （State Key Laboratory of Fine Chemicals，Dalian University of Technology，Dalian 116012，Liaoning，China） Abstract：Cationic polyacrylamide with quaternary ammonium group was used for cotton pretreatment with dip-pad-bake method and the obtained cotton was applied to salt-free dyeing of reactive dyes. The adsorption behaviors of C.I. Reactive Red 195，C.I. Reactive Red 19 and C.I. Reactive Yellow 145 on cationised cotton were investigated. Langmuir and Freundich adsorption models were applied to describe the equilibrium isotherms and isotherm constants were obtained. Langmuir-type adsorption isotherms were determined for reactive dyes on cationised cotton and the pseudo-second-order model provided a very good fitting for the three reactive dyes. The thermodynamic parameters including change in free energy（ΔG），enthalpy（ΔH），and entropy（ΔS）were also calculated and discussed. The color yield and fastness properties of the dyes on both fibers were also investigated and the satisfactory results showed the feasibility of the pretreatment method. Key words：cationic polyacrylamide with quaternary ammonium group；cotton；reactive dyes； salt-free dyeing 棉纤维具有穿着舒适、透气性好等优点，其用 量占纺织纤维总量的 60%以上，具有其它纺织产品 无法代替的地位[1]。活性染料是目前唯一能与纤维 形成共价键结合的一类染料，具有色谱齐全、颜色 鲜艳、牢度优异等优点，是棉纤维染色中应用最广 泛的染料之一[2]。由于活性染料为阴离子型染料， 而棉纤维在染浴中带有负电，所以染色过程中染料 与纤维间存在静电斥力，这将大大地降低染料的利 用率。为此，目前一般在染色过程中加入大量的无 机盐（氯化钠或硫酸钠），使其在染液中电离出大量 带正电荷的钠离子，与染料阴离子保持电荷中性， 消除染色过程中的静电斥力，以便染料分子与纤维