复合半导体光电解水制氢研究进展.PDFVIP

第 45 卷第 1 期 硅 酸 盐 学 报 Vol. 45 ，No. 1 2 0 1 7 年 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY January ，2017 DOI ：10.14062/j.issn.0454-5648.2017.01.14 综 合 评 述 复合半导体光电解水制氢研究进展 周俊琛，周 权，李建保，林仕伟 (海南大学材料与化工学院，热带岛屿资源先进材料教育部重点实验室，海口 570228) 摘 要：通过半导体光电解水生产氢气是将太阳能转化并储存为化学能的理想途径。但单一半导体由于自身的局限性很难在 水溶液中稳定并高效的分解水，通过半导体的复合，不仅提高了太阳光的吸收率，并且有效降低了载流子的复合，是一种提 高转化效率的有效方法。根据不同半导体复合后能带匹配和界面性质进行归类，介绍了复合半导体光解水的机理和制备工艺， 对其存在问题进行探讨并对发展前景进行了展望。 关键词：光解水；复合半导体；能带结构；电荷迁移 中图分类号：B33; TB34 文献标志码：A 文章编号：0454–5648(2017)01–096–10 网络出版时间：2016–12–12 09:52:14 网络出版地址：/kcms/detail/11.2310.TQ0952.007.html Developments on Composite Semiconductors for Hydrogen Production by Photoelectrical Water Splitting ZHOU Junchen, ZHOU Quan, LI Jianbao, LIN Shiwei (College of Materials and Chemical Engineering, Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, Haikou 570228, China) Abstract: Water splitting hydrogen production by semiconductor photocatalysts is an effective approach to convert solar energy into chemical energy. However, single semiconductor is difficult to split water efficiently due to itself limitations. Semiconductor coupling is an effective method of enhancing the conversion efficiency because it can enhance solar energy absorption and reduce the carrier recombination. This review classified the composite semiconductors and summarized research progress on their preparation methods and the related photocatalytic mechanisms according to the different types of semiconductor combinations. The present challenges were also discussed, and the perspective