氨氮浓度对次氯酸钠消毒中水的影响.docVIP

第 5卷 第 12期 环 境 工 程 学 报 Vol．5, No．122011年 12月 Dec．2011 氨氮浓度对次氯酸钠消毒中水的影响 祝 明 1 杨雅雯 2 赵 燕 1 朱百泉 1 李 佳 1 (1. 中国肉类食品综合研究中心 , 北京 100068; 2．北京市劳动保护科学研究所 , 北京 100054 摘 要 研究了氨氮浓度对次氯酸钠消毒中水的影响 , 讨论了中水氨氮浓度 、 氯胺浓度 、 总余氯浓度 、 消毒接触时间和 总大肠菌群指标的变化关系 。 结果表明 , 氨氮随消毒接触时间呈先降低再升高的趋势 , 中水氨氮浓度越高 , 其变化幅度越 小 , 反之 , 则变化幅度较大 ; 氯胺浓度随消毒接触时间的延长先升高再降低 , 而总余氯量则逐渐降低 , 并有一定的持续消毒 作用 ; 此外 , 总余氯随次氯酸钠投加量的增加呈先升高后降低再逐渐升高的趋势 , 整个反应过程符合折点加氯消毒理论 ; 当 次氯酸钠投加量与氨氮的比值 (以后简称 Cl /N 为 25/1时 , 氨氮消耗掉的次氯酸钠量最多 , 生成的总余氯量最少 ; 当 Cl /N比大于 25/1时 , 消毒后中水氨氮浓度为零 , 反之 , 则随 Cl /N比升高逐渐降低 ; 而当氨氮浓度相同时 , 中水消毒达标的主要 影响因素是水中总大肠菌群的数量 。 关键词 氨氮 次氯酸钠 消毒 中水 中图分类号 X703 文献标识码 A 文章编号 1673-9108(2011 12-2793-04Effect of ammonia nitrogen concentration on sodium hypochlorite disinfection of reclaimed water Zhu Ming 1 Yang Yawen 2 Zhao Yan 1 Zhu Baiquan 1 Li Jia 1 (1．China Meat Research Centre , Beijing 100068, China ; 2．Beijing Municipal Institute of Labor Protection , Beijing 100054, China Abstract The effect of ammonia nitrogen on the disinfection of reclaimed water with using sodium hypochlorite as the disinfector was studied．Other factors such as chloramine concentration , total chlorine concentration , reaction time were also considered．The results showed that the ammonia nitrogen concentration went up at the beginning , and then dropped．The higher initial ammonia nitrogen concentration , the lower its variation was．And the lower initial concentration , the higher variation was．And the concentration of chloramine went up at the beginning and then dropped till the end , and the chloramine had continual disinfection effect．The whole process was in accordance with break point chlorination disinfection theory．When the ratio of chlorine towards nitrogen was 25/1, ammonia nitrogen consumed the most sodium hypochlorite , and the total chlorine concentration was the lowest．When the ratio was high-er than 25/1, the ammonia nitrogen concentration was under the detection limit．When the ratio was lower than 25/1, the ammonia nitrogen concentration decrease