铜在北京土壤环境中的腐蚀行为.pdf

中国腐蚀与防护学报 Journal of Chinese Society for Corrosion and Protection 铜在北京土壤环境中的腐蚀行为 朱敏,杜翠薇,李晓刚,刘智勇,李月强,黄亮 (北京科技大学材料科学与工程学院 北京 100083) 摘要：通过现场试验(1 、2 、2.5 年)和电化学阻抗谱(EIS) 的测试，并结合腐蚀形貌宏观观察、SEM、XRD 及失重法对纯铜在北京土壤环境中的腐蚀行为及机理进行了研究。研究表明：现场埋样 1、2 、2.5 年的纯 铜的腐蚀特征均为非均匀的全面腐蚀，腐蚀程度较轻微。随埋样时间的延长，纯铜的腐蚀速率近乎以呈线 性关系减小，岛屿状腐蚀产物中的空隙等缺陷减少，其致密性有所改善。腐蚀产物均主要由Cu (CO )(OH) 、 2 3 2 CuO·3H2O、CuCl 组成。 关键词：纯铜；北京土壤；EIS ；腐蚀行为 中图分类号：TG172.4 文献标识码：A 文章编号：1005-4537(2012)xx-0000-00 Corrosion Behavior of Pure Copper in Beijing Soil Environment ZHU Min, DU Cuiwei, LI Xiaogang, LIU Zhiyong,LI Yueqiang, HUANG Liang, School of Materials Science and Engineering, University of Science and Technology Beijing, 1 v Beijing 100083 ，china 1 Abstract: The corrosion behavior of pure copper in Beijing soil environment was investigated by 7 4 burying test in nature field for one year, two years and two point five years, electrochemical 0 impedance spectroscopy(EIS), macro-morphology, SEM, XRD and weight-loss method. The 0 results showed that nonuniform general corrosion occurred mainly on the pure copper in Beijing . 1 soil, with the slight corrosion. The corrosion rate of pure copper nearly decreased linearly with the 1 6 increase of burying time, while the defects in island-like corrosion product reduced, and the 1 compactness of the corrosion product improved. The corrosion product mainly consisted of