石墨烯在锂电池应用.pdf

石墨烯在高能量密度锂离子电池中的应用 The Applications of Graphene Conductive Additive for High-Energy Li-ion Batteries 刘兆平 LIU Zhaoping 中科院宁波材料所 Ningbo Institute of Materials Technology and Engineering, CAS 2015-4-23 报告提纲 Outline  石墨烯导电剂的基 问题 Basic Questions On Graphene Conductive Additive  石墨烯微片制备技术进展 Preparation Technology Progress About Graphene  石墨烯导电剂的开发思路 Development Thinking of Graphene Conductive Additive  石墨烯导电剂的应用案例 Application Cases of Graphene Conductive Additive  石墨烯导电剂商业化的问题思考 Key Problems About Commercialization of Graphene Conductive Additive 2 导电剂新品种——石墨烯 Graphene, a new member of the conductive additive family 传统导电剂 高端导电剂 Conventional Conductive Additives Advanced Conductive Additives 导电碳黑 导电石墨 气相生长碳纤维 碳纳米管 石墨烯 Super P Li SFG6 VGCF CNTs Graphene 颗粒尺寸 Particle Size 40 nm 片径3-6 μm 直径150 nm 直径~10 nm 厚度 3nm 2 比表面积 SSA (m /g) 60 17 13 ~ 200 30 (BET) 粉体电导率 10 1000 1000 1000 1000 Conductivity (S/cm) 吸油值 DBP (ml/100g) 290 180 / ~200 2000 导电剂结构及导电机制 碳黑Super P ，刚性纳米颗粒 rigid 导电石墨SFG6 ，刚性微米颗粒 rigid 点与点接触，point-to-point 点与点接触，point-to-point 碳纳米管CNTs, 柔性 flexible 石墨烯Graphene ，柔性薄片 flexible 线与点接触