形变铜铁铬系复合材料大气腐蚀研究.docVIP

燕山大学工学硕士学位论文 摘要 PAGE IV PAGE V 摘 要 本文对铜基复合材料在模拟大气污染环境中的腐蚀行为进行了研究。 通过感应熔炼、铸造、锻造、热轧和冷拔制备了Cu-Fe-Cr-Ni系复合材料，包括Cu-18wt%Fe、Cu-15wt%Fe、Cu-16wt%Fe-2wt%Cr、Cu-10wt%SS四种原位(微观)复合材料和Cu-5vol%SS、Cu-10vol%SS两种宏观复合材料。 采用间歇式盐水喷雾试验和极化曲线测定，研究了Cu-18wt%Fe、Cu-15 wt%Fe、Cu-16wt%Fe-2wt%Cr三种原位(微观)复合材料和纯铜在三种模拟大气污染介质NaHSO3+NaCl、NaHSO3、NaCl中的腐蚀行为。同时研究了腐蚀对于材料的力学性能、导电性能和显微组织的影响。采用选择腐蚀技术，提出了原位复合材料中的纤维相，并测定了纤维相电极电位。模拟大气污染环境结果表明，NaHSO3对原位(微观)复合材料大气腐蚀的影响显著。Cr 的加入，可明显提高原位(微观)复合材料的耐大气腐蚀性能。其中Cu-16wt%Fe-2wt%Cr原位(微观)复合材料在模拟大气污染环境中耐蚀性最好。 采用同样的方法，研究了Cu-10wt%SS原位(微观)复合材料和Cu-5vol%SS、Cu-10vol%SS两种宏观复合材料和纯铜在三种模拟大气污染介质NaHSO3+NaCl、NaHSO3、NaCl中的腐蚀行为。模拟大气污染环境结果表明，NaHSO3对形变Cu-Fe-Cr-Ni系复合材料的大气腐蚀影响显著。Cu-10wt%SS原位(微观)复合材料在模拟污染大气中具有一定的耐蚀性。 关键词 Cu-Fe-Cr原位(微观)复合材料；Cu-Fe-Cr-Ni宏观复合材料； 大气腐蚀；盐水喷雾试验；极化曲线 Abstract In this paper, the corrosion behaviors of copper based composites in simulated atmospheric polluted environments were studied. Cu-Fe-Cr-Ni composites were manufactured by inductive melting, casting, forging, hot rolling and cold drawing, including Cu-18wt%Fe, Cu-15wt%Fe, Cu-16wt%Fe-2wt%Cr, Cu-10wt%SS in situ composites and Cu-5vol%SS, Cu-10vol%SS microcomposites. By means of salt spray tests and polarization curve analyses, the corrosion behaviors of Cu-18wt%Fe, Cu-15wt%Fe, Cu-16wt%Fe-2wt%Cr in situ composites and Cu in NaHSO3+NaCl, NaHSO3 or NaCl were studied. The effects of corrosion on mechanical properties, electrical properties and images of microstructures were investigated. The fibres were extracted from composites by use of a selective etching technique, and the electrode potential of the fibre was determinated. The results of simulated atmospheric polluted environments showed that NaHSO3 on atmospheric corrosion of the composites was obvious. The addition of Cr to the composites obviously improved the atmospheric corrosion resistance of in situ composites. In simulated atmospheric polluted environments, the atmospheric corrosion resistance of the Cu-16wt%Fe-2wt%Cr in situ composite was the best among