水处理剂聚合硫酸铁中六价铬的检测方法探讨.docVIP

中国卫生检验杂志2010年6月第20卷第6期 C h i nese Jou rnal ofH ea l th Laboratory Technol ogy , Jun 2010; Vo l20 N o 61275 论著 水处理剂聚合硫酸铁中六价铬的检测方法探讨 樊正, 张荣 (安徽省马鞍山市疾病预防控制中心, 安徽马鞍山 243000 [摘要] 目的:探讨水处理剂聚合硫酸铁中六价铬的检测方法, 提高分析结果的准确性。方法:用2m ol/L氢氧化钠溶 液对样品进行前处理, 采用石墨炉原子吸收法测定六价铬含量并找出最佳实验条件。结果:线性范围0 g /L~50 g /L,相关系数为0 9998, 检出限为0 049 g /L,相对标准偏差为1 73%~3 39%, 回收率为94 5%, 最佳灰化温度1100 、原子化温度2600 。结论:方法具有操作简便、快速、检出限低、灵敏度高、结果准确等优点, 适合于水处理剂聚合硫酸铁中六价铬的测定。 [关键词] 水处理剂; 聚合硫酸铁; 六价铬; 氢氧化钠; 石墨炉原子吸收法 [中图分类号] O 657 31 [文献标识码] A [文章编号] 1004-8685(2010 06-1275-04 Deter m ination of hexavalent chro m i n water treat m ent che m icals -poly ferric s ulfate FAN Zheng, Z HANG Rong (M aanshan Center f o r D isease Contro l and P reventi on , M aanshan 243000, Cha i n [Abstract] O bjective :T o develop a m et hod f o r deter m i nati on o f hexav alent chrom i n wa ter trea t m ent che m ica ls-poly ferr i c sulfate and advance t he verac it y of the results M ethod s :T he pre trea t m ent was pe rfor m ed usi ng 2m o l/Lsod i u m hydrox i de so l u -ti on , G raphite fu m ace atom ic abso rpti on spectrome try w as used to dete r m ina ti on of hexava l ent chro m i n this study and the best ex -per i m enta l cond iti ons w as f ound R es u lts :T he li nea r range w as 0 g /L~50 g /L, T he co rre l a ti on coeffi c i ent was 0 9998 T he li m its o f de tecti on w as 0 049 g /L The RS D was 1 73%~3 39% The rate of recove ry w as 94 5% T he best c i nera ti on te mper -a t ure was 1100 , atom iza tion te m pe rature was 2600 Conc l u sion :The m et hod has advantages o f si m ple operation , fast deter -m i nati on , l ow li m it o f detecti on , high sensiti v ity as w ell as accu rate resualts , and t herefore is su itab l e fo r de ter m i na ti on o f hexava -len t chro m i n w ater treat m ent che m ica ls-poly ferric suifa te [K ey words] W a ter treat m ent che m icals ; Po l y ferr i c sulfa te ; H exava lent chro m; Sod i u m hydrox ide ; G raph ite fu m ace a t om i c absorpti on spec trom etry 在地球上不存在天然元素