表面改性和混杂对超高分子量聚乙烯纤维环氧树脂复合材料.pdfVIP

第29 卷 第11 期 材 料 研 究 学 报 Vol. 29 No. 11 2 0 1 5 年 1 1 月 CHINESE JOURNAL OF MATERIALS RESEARCH November 2 0 1 5 表面改性和混杂对超高分子量聚乙烯纤维/ 环氧树脂复合材料性能的影响* 邱 军 王增义 孙 茜 高雪媛 (先进土木工程材料教育部重点实验室 同济大学材料科学与工程学院 上海 201804) 摘要采用紫外接枝和与芳纶纤维混杂的方式改善UHMWPE 纤维的缺点, 详细研究了接枝单体种类、浓度和纤维混杂等对 UHMWPE 纤维/环氧树脂复合材料性能的影响。结果表明, 以丙酮为溶剂采用一步接枝法在紫外光辐射下将丙烯酸接枝到 UHMWPE 纤维表面上, 可显著提高UHMWPE 纤维增强的复合材料的弯曲强度、冲击强度和拉伸强度; 随着接枝单体浓度 的提高弯曲强度和冲击强度没有明显的变化, 而拉伸强度不断提高。同时, 将UHMWPE 纤维与芳纶纤维混杂可提高其与树 脂基体生成的复合材料的耐热性。UHMWPE 纤维与芳纶纤维按1∶1 的质量比混杂, 混杂纤维增强的复合材料在90℃的形 变量比UHMWPE 纤维增强的复合材料减少66.7%, 显著提高了复合材料的耐热性。 关键词 复合材料, 紫外接枝, 混杂, UHMWPE 纤维, 芳纶纤维 分类号 TB332 文章编号 1005-3093(2015) 11-0807-07 Effect of Surface Modification and Hybridization of UHMWPE Fibers on Performance of their Composites with Epoxy Resin QIU Jun** WANG Zengyi SUN Qian GAO Xueyuan (Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China) *Supported by Shanghai Programs for Science and Technology Development No. 12521102204. Manuscript received May 7, 2015; in revised form July 4, 2015. **To whom correspondence should be addressed, Tel: (021 E-mail: qiujun@tongji.edu.cn ABSTRACT Ultra high molecular weight polyethylene (UHMWPE) fibers possess outstanding proper- ties such as high tensile strength and low density. However, their low surface polarity and poor heat resis- tance restrict the application of UHMWPE fibers as a reinforcing m