CCSD 超高压变质岩中金红石结构水(OH^-) 的傅里叶变.doc

CCSD超高压变质岩中金红石结构水（OH-1） 的傅里叶变换红外光谱测定及其地球动力学意义? ?本文得到国家自然科学基金重大项目（No、中国科学院同位素年代学和地球化学实验室合作基金(GIGIso-0504)和国家重大基础研究973项目（No.2003联合资助。 第一作者简介： 梁金龙，男，1967年生， 博士研究生，主要从事矿物学和矿床地球化学研究。E-mail: richardljl04@ ** 通讯作者，孙晓明, E-mail: eessxm@ 梁金龙1 孙晓明1,2** 徐莉1 翟伟1 汤倩1 梁业恒1 LIANG JinLong1, SUN XiaoMing1,2, XU Li1, ZHAI Wei1, TANG Qian1, LIANG YeHeng1 1中山大学地球科学系，广州 510275 2中国科学院同位素年代学和地球化学实验室, 广州 510640 Department of Earth Sciences, Sun Yat-Sen University, Guangzhou 510275, China Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China Liang JL, Sun XM, Xu L, Zhai W, Tang Q and Liang YH, 2006, Structural hydroxyl of rutile in UHP metamorphic rocks from Chinese Continental Scientific Drilling Project (CCSD) and areas nearby and it’s significance for geodynamics. Abstract The research of structural water in nominally anhydrous minerals (NAMs) is significant to understanding the fluid flow activity in ultra-high pressure metamorphism, the geodynamics in convergent continental margins and the water recycling in mantle. This study focus on the structural hydroxyl concentrations of rutile in eclogites from main-hole of the Chinese Continental Scientific drilling project(CCSD) and its areas nearby employing microscope Fourier infrared spectroscopy(FTIR) with unpolarized light. The rutile samples all exhibit a single sharp band at near 3280 cm-1, which is the structural hydroxyl(OH-1) absorption band, indicating water is structurally incorporated in rutiles. Calculation shows that the rutile is the “water” richest ultrahigh pressure mineral, and the “water” contents in rutiles are as high as 8826.31×10-6(wt%). In addition, “water” concentrations of inclusions rutiles are higher than intergranular ones, and the rutiles from fresh eclogites hold more “water” than those from retrograded eclogites, implying that the retrograded fluid might not be derived mainly from release of struct