Fe3O4磁性纳米材料的研究.pdfVIP

纳米 Fe3O 4 磁性材料的合成与现状 邹晓菊 （淮南师范学院化学与化工系 08 应化（ 1）班 淮南 232001 ） 【摘要】：本论文从 Fe 的空间构型 ,磁矩 ,磁化率，说明它具有磁性的原因。简 3O4 述纳米材料与纳米复合材料的特性， 具体介绍了纳米 Fe 磁性材料的制备方法， 3O4 主要有机械球磨法，水热法，微乳液法，超声沉淀法，水解法，湿化法。此外， 还研究了选取不同聚合物对纳米 Fe3O4 粒子表面进行修饰， 制备了四种类型的聚 合物修饰纳米 Fe 磁性复合材料，利用流变仪，红外光谱，热重分析，动态超 3O4 显微硬度仪测试表征的方法地所复合体系的结构及性能进行了研究。 最后利用生 物分子葡萄糖为还原剂 ,通过绿色化学合成方法制备得到了超顺磁性四氧化三铁 (Fe3O4)纳米颗粒；还利用原位还原法、共混包埋法、悬浮聚合法等方法分别制 备得到了双功能 Fe3O4/Se 一维纳米板束、 Fe3O4/Se/PANI 复合材料、双醛淀粉 包覆的和聚苯乙烯 -丙烯酸包覆的 Fe3O4磁性高分子微球。 【Abstract 】： This paper from the space configuration, Fe3O4 magnetic strength, susceptibility, explain it has magnetic reasons. Briefly nanometer material and the characteristics of nano composite materials, introduces the preparation of nanometer Fe3O4 magnetic material method, basically have mechanical ball grinding method, hydrothermal synthesis, microemulsion method, ultrasound depositing, hydrolysis method, moist method. In addition, also studied choosing different of nanometer particle surface of polymer modified Fe3O4 prepared, four types of polymer modified nano Fe3O4 magnetic composite materials, using rheometry, ir, thermogravimetric analysis, the dynamic super microhardness meter test method of compound characterized the land which the structure and properties of the system were studied. Finally, using the biological molecules glucose for reductant, and through the green chemical synthesis method preparation got super paramagnetic SanTie (four oxidation Fe3O4) nanoparticles; Also use the in situ reduction method and blending embedding law, suspension polymerization methods such as double function was obtained respectively