ESI离子源背景离子来源.docVIP

ESI离子源背景离子来源 m/z Ion Compound Source of Unknown 33 (M+H)+ methanol 42 (M+H)+ acetonitrile 59 (M+NH4)+ acetonitrile 64 (M+Na)+ acetonitrile 65 (2M+H)+ methanol 74 (M+H)+ dimethyl formamide 79 (M+H)+ DMSO 83 (2M+H)+ Acetonitrile 85 (M+H)+ d6‐DMSO 88 (M+Formic Acid+H)+ acetonitrile 101 (M+Na)+ DMSO 102 (M+H)+ triethylamine (TEA) 104/106 (M+Cu)+ acetonitrile 105 (2M+Na)+ acetonitrile 115 (M+dimethyl formamide+H)+ acetonitrile 120 (M+Na+CH3CN)+ DMSO 122 (M+H)+tris,tris(hydroxymethyl)aminomethane 123 (M+H)+ dimethylaminopyridine (DMAP) 130 (M+H)+ diisopropylethyl amine (DIPEA) 137 (M+CH3CN+NH4)+ DMSO 144 (M+H)+ tripropylamine (TPA) 145/147 (2M+Cu)+ acetonitrile 146 (3M+Na)+ acetonitrile 149 (M+H)+ phthalic anhydride 150 (M+H)+ phenyldiethylamine 153 (M+H)+1,8‐diazabicycloundec‐7‐ene(DBU) 157 (2M+H)+ DMSO 159 (M+Na)+ sodium trifluoroacetate 163 dimethyl phthalate 167 dioctyl phthalate 169 (2M+H)+ d6‐DMSO 171 (M+Na)+ phthalic anhydride 179 (2M+Na)+ DMSO 186 (M+H)+ tributylamine 195 (M+H)+ dimethyl phthalate 214 (M+H)+n‐butyl benzenesulfonamide (plastisizer) 225 (M+H)+ dicyclohexyl urea (DCU) 231 (M+NH3)+n‐butyl benzenesulfonamide(plastisizer) 236 (M+Na)+n‐butyl benzenesulfonamide(plastisizer) 239/241 + triethylamine 242 M+ tetrabutylammonium (C4H9)4N+ 243 M+ trityl cation 257 (3M+H)+ DMSO 267 (M+H)+ tributylphosphate 273 M+ monomethoxytrityl cation (MMT) 279 M+ triphenylphosphine oxide 279 M+ dibutylphthalate (plasticiser) 282 (M+H)+ oleamideslip agent inpolyethylene films 284 (M+H)+ stearamideslip agent inpolyethylene films 288 (M+H)+n,n‐bis(2‐hydroxyethyl)dodecanamide anti‐static agent 301 (M+Na)+ dibutylphthalate (plasticiser) 303 (M+Na)+ oleamideslip agent inpolyethylene films 317 (M+K)+ dibutylphthalate (plasticiser) 336 (M+H)+ tributyl tin formate 338 (M+H)+ erucamideslip agent inpolyethylene films 355 siloxane from silicacolumn 360 (M+Na)+ erucamideslip agent in polyethylene films 371 (M+H)+ decamethylcyclopentasiloxane 388 decamethylcyclopentasiloxane 391 (M+H)+ dii