《第六章 硅酸盐水泥熟料显微结构分析》.pptVIP

第六章 硅酸盐水泥熟料显微结构分析;一、熟料岩相分析的作用;二、硅酸盐水泥熟料的矿物组成;Figure 4-1. Modes of sample preparation: (1) single clinker, impregnated with epoxy resin, cut, and polished; (2) crushed clinker fragments, encapsulated and impregnated with epoxy, cut, and polished; (3) whole clinkers impregnated with epoxy and mounted on a thin film of epoxy on a glass microscope slide, cut and polished; (4) millimeter-size crushed clinkers, embedded in epoxy, ground, and polished; ;(5) cement, size graded by sedimentation in an alcohol-mineral spirits mixture in a glass vial, dried, impregnated with epoxy, cut, and polished; (6) drilled holes in an epoxy plug, filled individually with cement (a) extracted with a potassium hydroxide-sugar solution, (b) extracted with maleic acid, and ? unextracted—the plug has been cut and polished; (7) thin section of whole clinkers; section thickness is approximately 22 mm; (8) crushed clinker, 45- to 75- mm fraction, in Hyrax, for determination of the kiln parameters with the Ono Method. Scale divisions in mm. (S#A7094);四、硅酸盐水泥熟料的岩相形态;主要包括: Alite（简称阿利特或A矿）； Belite（简称贝利特或B矿）； 黑色中间相（C3A）； 白色中间相Celite（简称才利特或C矿，C4AF）； 少量的游离氧化钙（f-CaO）、方镁石、玻璃相等。 ; 1. A矿 （Alite）; 正常煅烧熟料中A矿晶体的大小约20-30μm，呈边棱平直，六角板，柱状的自形晶（图9-3）。 ;;图3 包晶结构的阿里特晶体 ; 图9-5是慢冷熟料A矿分解，周围环绕着析出的小颗粒C2S晶体的花环状结构。;;图9-6是受酸性溶液浸蚀后形成的港湾状结构； 图9-7是内外成份不同出现的环带结构，等等。 ; 在反光显微镜下， 用 1% 的 NH4Cl 水溶液浸蚀光片后A矿呈兰色； 用 1% 硝酸酒精浸蚀光片后，A矿呈棕色。;;;Uniform silicate distribution in polished clinker thin section showing angular, equant to elongated alite; round, clear belite with typical multidirectional lamellae; and a finely microcrystalline matrix of aluminate (C3A) and ferrite (C4AF). plane-polarized light Section thickness = 15 mm;Clinker thin section (approximately 15 mm thick) showing relatively large angular alite; smaller, round belite; and normal ferrite with its short slender intersecting crystals, between which the aluminate occurs (not visible at this magnification). Transmitted, plane-polarized light ;;;;2、