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Chapter 3
If ao were to increase, the
bandgap energy
would decrease and the material
would begin
to behave less like a
semiconductor and more
like a metal. If
ao were to
decrease, the
bandgap energy would increase and
the
material would begin to behave
more like an
insulator.
_______________________________________
Schrodingers wave equation is:
2
2
x, t
V x
x, t
2m
x2
j
x, t
t
Assume the solution is of the form:
x, t
u x exp j kx
E
t
Region I:
V x
0 . Substituting
the
assumed solution into the wave
equation, we
obtain:
2
E
2m
x
jku
x exp
j
kx
t
u x exp j kx
E
t
x
j
jE
u x exp
j
kx
E t
which becomes
2
2 u
E
2m
jk
x exp
j
kx
t
2 jk
u x exp
j
kx
E
t
x
2 u x
exp j
E
t
x2
kx
Eu x
exp
j kx
E t
This equation may be written as
k
2
u x
u x
2 u x
2mE
2 jk
x
2
2
u x 0
x
Setting
u x
u1
x
for region I,
the equation
becomes:
d 2 u1 x
2 jk du1 x
k 2
2 u1 x 0
dx2
dx
where
2
2mE
2
In Region II,
V x
VO . Assume the
same
form of the solution:
x, t
u x exp
j
kx
E
t
Substituting into Schrodingers
wave
equation, we find:
2
2 u
E
jk
x exp
j
kx
t
2m
2 jk
u x exp
j
kx
E
t
x
2
2x exp j
u
kx
E
t
x
V O u x
exp
j
kx
E t
Eu
x exp
j
kx
E
t
This equation can be written as:
k 2u x 2 jk
u x
2u x
x
x2
2mVO
u x
2mE
u x 0
2
2
Setting u x u 2 x for region II, this
equation becomes
d 2 u 2
x
du2
x
dx2
2 jk
dx
k
2
2 2mVO
u2 x 0
2
where again
2mE
2
We have
2
2 jk du1 x
d u1 x
k 2
2 u1 x 0
dx2
dx
Assume the solution is of the form:
u1 x
A exp j
k x
B exp
j
k x
The first derivative is
du1 x
j
k A exp j
k x
dx
j
k B exp
j
k x
and the second derivative becomes
d 2 u1 x
j
k
2
k x
dx2
A exp j
2 B exp
j
k
j
k x
Substituting these equations into
the
differential equation, we find
k
2 A exp
j
k x
2
B exp
j
k
x
k
2 jk
j
k A exp j
k x
j
k B exp
j
k x
k 2
2
A exp j
k x
B exp
j
k x
0
Combining terms, we obtain
2
2 k k 2
2k
k
k 2
2
A exp j
k x
2
2 k k 2
2k
k
k 2
2
B exp
j
k x
0
We find that
0
0
For the differential equation in
u 2 x
and the
proposed solution, the proced
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